On high dose nitrogen implantation of PVD titanium nitride

A 3 × 3 matrix of samples has been ion implanted with nitrogen at low-to-high doses and low-to-high current densities (dose rates). All samples show surface exfoliation which results in a loss of the implanted nitrogen and a consequent loss of the wear-resistant properties—a condition of over-implan...

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Veröffentlicht in:Surface & coatings technology 2006-05, Vol.200 (20), p.5915-5920
Hauptverfasser: Sharkeev, Yurii P., Bull, Steve J., Perry, Anthony J., Klingenberg, Melissa L., Fortuna, Sergei V., Michler, Markus, Manory, Rafael R., Shulepov, Ivan A.
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container_end_page 5920
container_issue 20
container_start_page 5915
container_title Surface & coatings technology
container_volume 200
creator Sharkeev, Yurii P.
Bull, Steve J.
Perry, Anthony J.
Klingenberg, Melissa L.
Fortuna, Sergei V.
Michler, Markus
Manory, Rafael R.
Shulepov, Ivan A.
description A 3 × 3 matrix of samples has been ion implanted with nitrogen at low-to-high doses and low-to-high current densities (dose rates). All samples show surface exfoliation which results in a loss of the implanted nitrogen and a consequent loss of the wear-resistant properties—a condition of over-implantation reminiscent of that observed with metal ion implantation. There is an uptake of post-implantation oxygen which is believed to form an amorphous TiO 2 component in the surface leading to the well-established low frictional properties. This uptake decreases as the dose rate is increased and would lead to a loss of wear resistant properties. The work confirms that a dose of 3 × 10 17 ions cm − 2 is optimal provided that the dose rate does not exceed the present industrial standard.
doi_str_mv 10.1016/j.surfcoat.2005.09.010
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source ScienceDirect Journals (5 years ago - present)
subjects Ion implantation
Nitrogen ions
Surface treatment
Titanium nitride
title On high dose nitrogen implantation of PVD titanium nitride
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