Rheological and electrical properties of polycarbonate/multi-walled carbon nanotube composites

Rheological and electrical properties of the polycarbonate (PC)/multi-walled carbon nanotube (MWNT) were studied. The MWNT was funtoinalized by treating with the hydrogen peroxide (H 2O 2). The H 2O 2 treated MWNT was dried by thermal and freeze drying methods. From the morphological studies, the de...

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Veröffentlicht in:Polymer (Guilford) 2006-05, Vol.47 (12), p.4434-4439
Hauptverfasser: Sung, Y.T., Han, M.S., Song, K.H., Jung, J.W., Lee, H.S., Kum, C.K., Joo, J., Kim, W.N.
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Sprache:eng
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Zusammenfassung:Rheological and electrical properties of the polycarbonate (PC)/multi-walled carbon nanotube (MWNT) were studied. The MWNT was funtoinalized by treating with the hydrogen peroxide (H 2O 2). The H 2O 2 treated MWNT was dried by thermal and freeze drying methods. From the morphological studies, the degree of entanglement of the MWNT was decreased after treating with the H 2O 2. For the H 2O 2 treated MWNT (thermal drying), the length of the MWNT was shortened compared that of the H 2O 2 treated MWNT (freeze drying). The rheological and electrical properties of the PC/MWNT (H 2O 2 treated) composites increased compared that of the PC/MWNT (untreated) composites. Also, the electrical conductivity showed higher value for the PC/MWNT (H 2O 2 treated, freeze drying) composites compared that of the PC/MWNT (H 2O 2 treated, thermal drying) composites. From the results of the morphological, rheological, and electrical properties of the PC/MWNT composites, it is suggested that the electrical and rheological properties of the PC/MWNT composites are affected by the MWNT–MWNT network structure, which is related with the MWNT morphologies such as the degree of aggregation and aspect ratio of the MWNT.
ISSN:0032-3861
1873-2291
DOI:10.1016/j.polymer.2006.04.008