An organic semiconductor and conduction mechanism: N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound

The electrical conductivity, optical and thermal properties of newly synthesized N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound have been investigated. In order to find an explanation for the conduction mechanism, different conduction models were tested. The best fit of the experimenta...

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Veröffentlicht in:Physica. B, Condensed matter Condensed matter, 2004-12, Vol.353 (3), p.223-229
Hauptverfasser: Yakuphanoglu, F., Gorgulu, A.O., Cukurovali, A.
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container_title Physica. B, Condensed matter
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creator Yakuphanoglu, F.
Gorgulu, A.O.
Cukurovali, A.
description The electrical conductivity, optical and thermal properties of newly synthesized N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound have been investigated. In order to find an explanation for the conduction mechanism, different conduction models were tested. The best fit of the experimental conductivity data of the compound was obtained with theoretical prediction and it is found that while the conduction mechanism at lower temperatures corresponds to three-dimensional hopping conduction, the conduction mechanism at higher temperatures corresponds to hopping of thermally activated carriers into the band tails. The optical band gap of the compound was determined by means of the optical absorption spectra. Thermal properties and kinetic parameters such as activation energy, entropy and enthalpy based on thermogravimetric data were also determined.
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subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Conductivity
Conductivity of specific materials
Electronic transport in condensed matter
Exact sciences and technology
Heat capacities of solids
Optical absorption
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of bulk materials and thin films
Organic semiconductors
Physics
Polymers
organic compounds (including organic semiconductors)
TGA
Thermal properties of condensed matter
Thermal properties of crystalline solids
title An organic semiconductor and conduction mechanism: N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound
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