An organic semiconductor and conduction mechanism: N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound
The electrical conductivity, optical and thermal properties of newly synthesized N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound have been investigated. In order to find an explanation for the conduction mechanism, different conduction models were tested. The best fit of the experimenta...
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Veröffentlicht in: | Physica. B, Condensed matter Condensed matter, 2004-12, Vol.353 (3), p.223-229 |
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creator | Yakuphanoglu, F. Gorgulu, A.O. Cukurovali, A. |
description | The electrical conductivity, optical and thermal properties of newly synthesized N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound have been investigated. In order to find an explanation for the conduction mechanism, different conduction models were tested. The best fit of the experimental conductivity data of the compound was obtained with theoretical prediction and it is found that while the conduction mechanism at lower temperatures corresponds to three-dimensional hopping conduction, the conduction mechanism at higher temperatures corresponds to hopping of thermally activated carriers into the band tails. The optical band gap of the compound was determined by means of the optical absorption spectra. Thermal properties and kinetic parameters such as activation energy, entropy and enthalpy based on thermogravimetric data were also determined. |
doi_str_mv | 10.1016/j.physb.2004.09.099 |
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In order to find an explanation for the conduction mechanism, different conduction models were tested. The best fit of the experimental conductivity data of the compound was obtained with theoretical prediction and it is found that while the conduction mechanism at lower temperatures corresponds to three-dimensional hopping conduction, the conduction mechanism at higher temperatures corresponds to hopping of thermally activated carriers into the band tails. The optical band gap of the compound was determined by means of the optical absorption spectra. Thermal properties and kinetic parameters such as activation energy, entropy and enthalpy based on thermogravimetric data were also determined.</description><identifier>ISSN: 0921-4526</identifier><identifier>EISSN: 1873-2135</identifier><identifier>DOI: 10.1016/j.physb.2004.09.099</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Conductivity ; Conductivity of specific materials ; Electronic transport in condensed matter ; Exact sciences and technology ; Heat capacities of solids ; Optical absorption ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Optical properties of bulk materials and thin films ; Organic semiconductors ; Physics ; Polymers; organic compounds (including organic semiconductors) ; TGA ; Thermal properties of condensed matter ; Thermal properties of crystalline solids</subject><ispartof>Physica. 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B, Condensed matter</title><description>The electrical conductivity, optical and thermal properties of newly synthesized N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound have been investigated. In order to find an explanation for the conduction mechanism, different conduction models were tested. The best fit of the experimental conductivity data of the compound was obtained with theoretical prediction and it is found that while the conduction mechanism at lower temperatures corresponds to three-dimensional hopping conduction, the conduction mechanism at higher temperatures corresponds to hopping of thermally activated carriers into the band tails. The optical band gap of the compound was determined by means of the optical absorption spectra. 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B, Condensed matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yakuphanoglu, F.</au><au>Gorgulu, A.O.</au><au>Cukurovali, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An organic semiconductor and conduction mechanism: N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound</atitle><jtitle>Physica. B, Condensed matter</jtitle><date>2004-12-15</date><risdate>2004</risdate><volume>353</volume><issue>3</issue><spage>223</spage><epage>229</epage><pages>223-229</pages><issn>0921-4526</issn><eissn>1873-2135</eissn><abstract>The electrical conductivity, optical and thermal properties of newly synthesized N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound have been investigated. In order to find an explanation for the conduction mechanism, different conduction models were tested. The best fit of the experimental conductivity data of the compound was obtained with theoretical prediction and it is found that while the conduction mechanism at lower temperatures corresponds to three-dimensional hopping conduction, the conduction mechanism at higher temperatures corresponds to hopping of thermally activated carriers into the band tails. The optical band gap of the compound was determined by means of the optical absorption spectra. Thermal properties and kinetic parameters such as activation energy, entropy and enthalpy based on thermogravimetric data were also determined.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.physb.2004.09.099</doi><tpages>7</tpages></addata></record> |
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subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Conductivity Conductivity of specific materials Electronic transport in condensed matter Exact sciences and technology Heat capacities of solids Optical absorption Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of bulk materials and thin films Organic semiconductors Physics Polymers organic compounds (including organic semiconductors) TGA Thermal properties of condensed matter Thermal properties of crystalline solids |
title | An organic semiconductor and conduction mechanism: N-[5-methyl-1,3,4-tiyodiazole-2-yl] ditiyocarbamate compound |
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