Nanocharacterization of electrocoated polymers on carbon fibers
Electropolymerization of carbazole and its copolymers onto carbon fibers were performed by potentiodynamic and potentiostatic methods. Electrocoated polymer thin films on carbon fiber microelectrodes (CFME) were characterized by combination of a variety of techniques, i.e., cyclo-voltammetry, electr...
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| Veröffentlicht in: | Microelectronic engineering 2006-04, Vol.83 (4), p.1534-1537 |
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| container_title | Microelectronic engineering |
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| creator | Sarac, A. Sezai |
| description | Electropolymerization of carbazole and its copolymers onto carbon fibers were performed by potentiodynamic and potentiostatic methods. Electrocoated polymer thin films on carbon fiber microelectrodes (CFME) were characterized by combination of a variety of techniques, i.e., cyclo-voltammetry, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy (XPS), reflectance FTIR spectroscopy (FTIR-ATR). From XPS results the peak at 285.7
eV is assigned to C
S bonding, for the poly[methylthiophene-co-carbazole]. Two distinct S2p peaks in a ratio of 3/2 was observed, which can be assigned to S in polaronic (binding energy: ∼164.7
eV) and S in bipolaronic forms. Broad band in FTIR-ATR centred in ∼3100
cm
−1 supports these findings. S and N contents of copolymeric films (XPS) formed (at different initial feed ratio of monomers [Cz]
0/[MeTh]
0
=
0.35–1.85) on the CFME surface copolymeric composition was found to be ranging from 1 to 16 carbazole unit against 1 MeTh unit in the resulting chain. |
| doi_str_mv | 10.1016/j.mee.2006.01.229 |
| format | Article |
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eV is assigned to C
S bonding, for the poly[methylthiophene-co-carbazole]. Two distinct S2p peaks in a ratio of 3/2 was observed, which can be assigned to S in polaronic (binding energy: ∼164.7
eV) and S in bipolaronic forms. Broad band in FTIR-ATR centred in ∼3100
cm
−1 supports these findings. S and N contents of copolymeric films (XPS) formed (at different initial feed ratio of monomers [Cz]
0/[MeTh]
0
=
0.35–1.85) on the CFME surface copolymeric composition was found to be ranging from 1 to 16 carbazole unit against 1 MeTh unit in the resulting chain.</description><identifier>ISSN: 0167-9317</identifier><identifier>EISSN: 1873-5568</identifier><identifier>DOI: 10.1016/j.mee.2006.01.229</identifier><identifier>CODEN: MIENEF</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Carbon fibers ; Coating, metallization, dyeing ; Electropolymerization ; Exact sciences and technology ; Machinery and processing ; Nanomodification ; Plastics ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>Microelectronic engineering, 2006-04, Vol.83 (4), p.1534-1537</ispartof><rights>2006 Elsevier B.V.</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-49af79fa3cca3c3b94ad461d29eb8fe1095dd669e0af9439c108be4d5072687d3</citedby><cites>FETCH-LOGICAL-c358t-49af79fa3cca3c3b94ad461d29eb8fe1095dd669e0af9439c108be4d5072687d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.mee.2006.01.229$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,3536,23910,23911,25119,27903,27904,45974</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17773574$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Sarac, A. Sezai</creatorcontrib><title>Nanocharacterization of electrocoated polymers on carbon fibers</title><title>Microelectronic engineering</title><description>Electropolymerization of carbazole and its copolymers onto carbon fibers were performed by potentiodynamic and potentiostatic methods. Electrocoated polymer thin films on carbon fiber microelectrodes (CFME) were characterized by combination of a variety of techniques, i.e., cyclo-voltammetry, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy (XPS), reflectance FTIR spectroscopy (FTIR-ATR). From XPS results the peak at 285.7
eV is assigned to C
S bonding, for the poly[methylthiophene-co-carbazole]. Two distinct S2p peaks in a ratio of 3/2 was observed, which can be assigned to S in polaronic (binding energy: ∼164.7
eV) and S in bipolaronic forms. Broad band in FTIR-ATR centred in ∼3100
cm
−1 supports these findings. S and N contents of copolymeric films (XPS) formed (at different initial feed ratio of monomers [Cz]
0/[MeTh]
0
=
0.35–1.85) on the CFME surface copolymeric composition was found to be ranging from 1 to 16 carbazole unit against 1 MeTh unit in the resulting chain.</description><subject>Applied sciences</subject><subject>Carbon fibers</subject><subject>Coating, metallization, dyeing</subject><subject>Electropolymerization</subject><subject>Exact sciences and technology</subject><subject>Machinery and processing</subject><subject>Nanomodification</subject><subject>Plastics</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0167-9317</issn><issn>1873-5568</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQQIMouK7-AG-96K01adqmwYPI4hcsetFzmCYTzNI2a9IV1l9vll3w5iEMmXkzwzxCLhktGGXNzaoYEIuS0qagrChLeURmrBU8r-umPSazxIhcciZOyVmMK5r-FW1n5O4VRq8_IYCeMLgfmJwfM28z7FFPwWsPE5ps7fvtgCFmqaghdClY16XEOTmx0Ee8OMQ5-Xh8eF8858u3p5fF_TLXvG6nvJJghbTAtU6Pd7ICUzXMlBK71iKjsjamaSRSsLLiUjPadliZmoqyaYXhc3K9n7sO_muDcVKDixr7Hkb0m6hKWZUiXZRAtgd18DEGtGod3ABhqxhVO1VqpZIqtVOlKFNJVeq5OgyHqKG3AUbt4l-jEILXokrc7Z7DdOm3w6CidjhqNC4kW8p498-WXwpifxg</recordid><startdate>20060401</startdate><enddate>20060401</enddate><creator>Sarac, A. Sezai</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20060401</creationdate><title>Nanocharacterization of electrocoated polymers on carbon fibers</title><author>Sarac, A. Sezai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-49af79fa3cca3c3b94ad461d29eb8fe1095dd669e0af9439c108be4d5072687d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Carbon fibers</topic><topic>Coating, metallization, dyeing</topic><topic>Electropolymerization</topic><topic>Exact sciences and technology</topic><topic>Machinery and processing</topic><topic>Nanomodification</topic><topic>Plastics</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sarac, A. Sezai</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Microelectronic engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sarac, A. Sezai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nanocharacterization of electrocoated polymers on carbon fibers</atitle><jtitle>Microelectronic engineering</jtitle><date>2006-04-01</date><risdate>2006</risdate><volume>83</volume><issue>4</issue><spage>1534</spage><epage>1537</epage><pages>1534-1537</pages><issn>0167-9317</issn><eissn>1873-5568</eissn><coden>MIENEF</coden><abstract>Electropolymerization of carbazole and its copolymers onto carbon fibers were performed by potentiodynamic and potentiostatic methods. Electrocoated polymer thin films on carbon fiber microelectrodes (CFME) were characterized by combination of a variety of techniques, i.e., cyclo-voltammetry, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy (XPS), reflectance FTIR spectroscopy (FTIR-ATR). From XPS results the peak at 285.7
eV is assigned to C
S bonding, for the poly[methylthiophene-co-carbazole]. Two distinct S2p peaks in a ratio of 3/2 was observed, which can be assigned to S in polaronic (binding energy: ∼164.7
eV) and S in bipolaronic forms. Broad band in FTIR-ATR centred in ∼3100
cm
−1 supports these findings. S and N contents of copolymeric films (XPS) formed (at different initial feed ratio of monomers [Cz]
0/[MeTh]
0
=
0.35–1.85) on the CFME surface copolymeric composition was found to be ranging from 1 to 16 carbazole unit against 1 MeTh unit in the resulting chain.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.mee.2006.01.229</doi><tpages>4</tpages></addata></record> |
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| identifier | ISSN: 0167-9317 |
| ispartof | Microelectronic engineering, 2006-04, Vol.83 (4), p.1534-1537 |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Carbon fibers Coating, metallization, dyeing Electropolymerization Exact sciences and technology Machinery and processing Nanomodification Plastics Polymer industry, paints, wood Technology of polymers |
| title | Nanocharacterization of electrocoated polymers on carbon fibers |
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