Preparation of photoluminescent nano‐biocomposite nacre from graphene oxide and polylactic acid
Nano‐biocomposites of inorganic and organic components wereprepared to produce long‐persistent phosphorescent artificial nacre‐like materials. Biodegradable polylactic acid (PLA), graphene oxide (GO), and nanoparticles (13–20 nm) of lanthanide‐doped aluminate pigment (NLAP) were used in a simple pro...
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| Veröffentlicht in: | Luminescence (Chichester, England) England), 2024-03, Vol.39 (3), p.e4688-n/a |
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| creator | El‐Newehy, Mohamed H. Aldalbahi, Ali Thamer, Badr M. Abdulhameed, Meera Moydeen |
| description | Nano‐biocomposites of inorganic and organic components wereprepared to produce long‐persistent phosphorescent artificial nacre‐like materials. Biodegradable polylactic acid (PLA), graphene oxide (GO), and nanoparticles (13–20 nm) of lanthanide‐doped aluminate pigment (NLAP) were used in a simple production procedure of an organic/inorganic hybrid nano‐biocomposite. Both polylactic acid and GO nanosheets were chemically modified to form covalent and hydrogen bonding. The high toughness, good tensile strength, and great endurance of those bonds were achieved by their interactions at the interfaces. Long‐persistent and reversible photoluminescence was shown by the prepared nacre substrates. Upon excitation at 365 nm, the nacre substrates generated an emission peak at 517 nm. When ultraviolet light was shone on luminescent nacres, they displayed a bright green colour. The high superhydrophobicity of the generated nacres was obtained without altering their mechanical characteristics.
Polylactic acid‐based photochromic and afterglow artificial nacre was prepared. Graphene oxide nanosheets were applied as a cross‐linking agent. Lanthanide aluminate nanoparticles (13–20 nm) were embedded into colorless nacre as a photoluminescent agent. Biodegradable smart nacre showed reversible color change to green under UV irradiation. Photoluminescent nano‐biocomposite nacre exhibited superhydrophobicity and UV protection. |
| doi_str_mv | 10.1002/bio.4688 |
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Polylactic acid‐based photochromic and afterglow artificial nacre was prepared. Graphene oxide nanosheets were applied as a cross‐linking agent. Lanthanide aluminate nanoparticles (13–20 nm) were embedded into colorless nacre as a photoluminescent agent. Biodegradable smart nacre showed reversible color change to green under UV irradiation. Photoluminescent nano‐biocomposite nacre exhibited superhydrophobicity and UV protection.</description><identifier>ISSN: 1522-7235</identifier><identifier>EISSN: 1522-7243</identifier><identifier>DOI: 10.1002/bio.4688</identifier><identifier>PMID: 38444125</identifier><language>eng</language><publisher>England: Wiley Subscription Services, Inc</publisher><subject>Biodegradation ; Biomedical materials ; Bonding strength ; Calcium carbonate ; Composite materials ; Graphene ; Graphite ; Hydrogen bonding ; Hydrophobicity ; Interfaces ; Mechanical properties ; Nacre ; Nanoparticles ; Phosphorescence ; Photoluminescence ; Photons ; Polyesters ; Polylactic acid ; rare‐earth‐doped aluminate ; smart nacre ; Substrates ; superhydrophobicity ; Tensile strength ; Ultraviolet radiation</subject><ispartof>Luminescence (Chichester, England), 2024-03, Vol.39 (3), p.e4688-n/a</ispartof><rights>2024 John Wiley & Sons Ltd.</rights><rights>2024 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c3108-9bc646d954a41a67bc838938c1470ba16b514422ea95c4f06a827e9d1fa4d8513</cites><orcidid>0000-0002-4265-0701</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fbio.4688$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fbio.4688$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38444125$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>El‐Newehy, Mohamed H.</creatorcontrib><creatorcontrib>Aldalbahi, Ali</creatorcontrib><creatorcontrib>Thamer, Badr M.</creatorcontrib><creatorcontrib>Abdulhameed, Meera Moydeen</creatorcontrib><title>Preparation of photoluminescent nano‐biocomposite nacre from graphene oxide and polylactic acid</title><title>Luminescence (Chichester, England)</title><addtitle>Luminescence</addtitle><description>Nano‐biocomposites of inorganic and organic components wereprepared to produce long‐persistent phosphorescent artificial nacre‐like materials. Biodegradable polylactic acid (PLA), graphene oxide (GO), and nanoparticles (13–20 nm) of lanthanide‐doped aluminate pigment (NLAP) were used in a simple production procedure of an organic/inorganic hybrid nano‐biocomposite. Both polylactic acid and GO nanosheets were chemically modified to form covalent and hydrogen bonding. The high toughness, good tensile strength, and great endurance of those bonds were achieved by their interactions at the interfaces. Long‐persistent and reversible photoluminescence was shown by the prepared nacre substrates. Upon excitation at 365 nm, the nacre substrates generated an emission peak at 517 nm. When ultraviolet light was shone on luminescent nacres, they displayed a bright green colour. The high superhydrophobicity of the generated nacres was obtained without altering their mechanical characteristics.
Polylactic acid‐based photochromic and afterglow artificial nacre was prepared. Graphene oxide nanosheets were applied as a cross‐linking agent. Lanthanide aluminate nanoparticles (13–20 nm) were embedded into colorless nacre as a photoluminescent agent. Biodegradable smart nacre showed reversible color change to green under UV irradiation. Photoluminescent nano‐biocomposite nacre exhibited superhydrophobicity and UV protection.</description><subject>Biodegradation</subject><subject>Biomedical materials</subject><subject>Bonding strength</subject><subject>Calcium carbonate</subject><subject>Composite materials</subject><subject>Graphene</subject><subject>Graphite</subject><subject>Hydrogen bonding</subject><subject>Hydrophobicity</subject><subject>Interfaces</subject><subject>Mechanical properties</subject><subject>Nacre</subject><subject>Nanoparticles</subject><subject>Phosphorescence</subject><subject>Photoluminescence</subject><subject>Photons</subject><subject>Polyesters</subject><subject>Polylactic acid</subject><subject>rare‐earth‐doped aluminate</subject><subject>smart nacre</subject><subject>Substrates</subject><subject>superhydrophobicity</subject><subject>Tensile strength</subject><subject>Ultraviolet radiation</subject><issn>1522-7235</issn><issn>1522-7243</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp1kMtKxTAQhoMo3sEnkIAbNz0maZKmSxVvIOhC12Waphppk5q06Nn5CD6jT2KOVxBczTB8fDPzI7RDyYwSwg5q62dcKrWE1qlgLCsYz5d_-lysoY0YHwghUspyFa3linNOmVhHcB3MAAFG6x32LR7u_ei7qbfORG3ciB04__bymjZo3w8-2tGkmQ4Gt8H3-C7AcG-cwf7ZNgaDa_Dgu3kHerQag7bNFlppoYtm-6tuotvTk5vj8-zy6uzi-PAy0zklKitrLblsSsGBU5BFrVWuylxpygtSA5W1oJwzZqAUmrdEgmKFKRvaAm-UoPkm2v_0DsE_TiaOVW_TC10HzvgpVizJmBJcsoTu_UEf_BRcui5RRclJzoX8FergYwymrYZgewjzipJqEXuVQqkWsSd090s41b1pfsDvnBOQfQJPtjPzf0XV0cXVh_Adm8SMjA</recordid><startdate>202403</startdate><enddate>202403</enddate><creator>El‐Newehy, Mohamed H.</creator><creator>Aldalbahi, Ali</creator><creator>Thamer, Badr M.</creator><creator>Abdulhameed, Meera Moydeen</creator><general>Wiley Subscription Services, Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QP</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>7U7</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H95</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L.G</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4265-0701</orcidid></search><sort><creationdate>202403</creationdate><title>Preparation of photoluminescent nano‐biocomposite nacre from graphene oxide and polylactic acid</title><author>El‐Newehy, Mohamed H. ; Aldalbahi, Ali ; Thamer, Badr M. ; Abdulhameed, Meera Moydeen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3108-9bc646d954a41a67bc838938c1470ba16b514422ea95c4f06a827e9d1fa4d8513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Biodegradation</topic><topic>Biomedical materials</topic><topic>Bonding strength</topic><topic>Calcium carbonate</topic><topic>Composite materials</topic><topic>Graphene</topic><topic>Graphite</topic><topic>Hydrogen bonding</topic><topic>Hydrophobicity</topic><topic>Interfaces</topic><topic>Mechanical properties</topic><topic>Nacre</topic><topic>Nanoparticles</topic><topic>Phosphorescence</topic><topic>Photoluminescence</topic><topic>Photons</topic><topic>Polyesters</topic><topic>Polylactic acid</topic><topic>rare‐earth‐doped aluminate</topic><topic>smart nacre</topic><topic>Substrates</topic><topic>superhydrophobicity</topic><topic>Tensile strength</topic><topic>Ultraviolet radiation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>El‐Newehy, Mohamed H.</creatorcontrib><creatorcontrib>Aldalbahi, Ali</creatorcontrib><creatorcontrib>Thamer, Badr M.</creatorcontrib><creatorcontrib>Abdulhameed, Meera Moydeen</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Calcium & Calcified Tissue Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 1: Biological Sciences & Living Resources</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Luminescence (Chichester, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>El‐Newehy, Mohamed H.</au><au>Aldalbahi, Ali</au><au>Thamer, Badr M.</au><au>Abdulhameed, Meera Moydeen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of photoluminescent nano‐biocomposite nacre from graphene oxide and polylactic acid</atitle><jtitle>Luminescence (Chichester, England)</jtitle><addtitle>Luminescence</addtitle><date>2024-03</date><risdate>2024</risdate><volume>39</volume><issue>3</issue><spage>e4688</spage><epage>n/a</epage><pages>e4688-n/a</pages><issn>1522-7235</issn><eissn>1522-7243</eissn><abstract>Nano‐biocomposites of inorganic and organic components wereprepared to produce long‐persistent phosphorescent artificial nacre‐like materials. Biodegradable polylactic acid (PLA), graphene oxide (GO), and nanoparticles (13–20 nm) of lanthanide‐doped aluminate pigment (NLAP) were used in a simple production procedure of an organic/inorganic hybrid nano‐biocomposite. Both polylactic acid and GO nanosheets were chemically modified to form covalent and hydrogen bonding. The high toughness, good tensile strength, and great endurance of those bonds were achieved by their interactions at the interfaces. Long‐persistent and reversible photoluminescence was shown by the prepared nacre substrates. Upon excitation at 365 nm, the nacre substrates generated an emission peak at 517 nm. When ultraviolet light was shone on luminescent nacres, they displayed a bright green colour. The high superhydrophobicity of the generated nacres was obtained without altering their mechanical characteristics.
Polylactic acid‐based photochromic and afterglow artificial nacre was prepared. Graphene oxide nanosheets were applied as a cross‐linking agent. Lanthanide aluminate nanoparticles (13–20 nm) were embedded into colorless nacre as a photoluminescent agent. Biodegradable smart nacre showed reversible color change to green under UV irradiation. Photoluminescent nano‐biocomposite nacre exhibited superhydrophobicity and UV protection.</abstract><cop>England</cop><pub>Wiley Subscription Services, Inc</pub><pmid>38444125</pmid><doi>10.1002/bio.4688</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-4265-0701</orcidid></addata></record> |
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| ispartof | Luminescence (Chichester, England), 2024-03, Vol.39 (3), p.e4688-n/a |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Biodegradation Biomedical materials Bonding strength Calcium carbonate Composite materials Graphene Graphite Hydrogen bonding Hydrophobicity Interfaces Mechanical properties Nacre Nanoparticles Phosphorescence Photoluminescence Photons Polyesters Polylactic acid rare‐earth‐doped aluminate smart nacre Substrates superhydrophobicity Tensile strength Ultraviolet radiation |
| title | Preparation of photoluminescent nano‐biocomposite nacre from graphene oxide and polylactic acid |
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