Ba10In2Mn11Si3O12S18: First Hexanary Oxychalcogenide Containing an Infrequent Three-Dimensional Noncentrosysmmetric Framework

Ba10In2Mn11Si3O12S18: First Hexanary Oxychalcogenide Containing an Infrequent Three-Dimensional Noncentrosysmmetric Framework

Noncentrosymmetric (NCS) oxychalcogenides have attracted great attention in recent years due to their immense potential as candidates for IR nonlinear-optical (NLO) applications. Despite notable advancements in this field, the discovery of oxychalcogenides with three-dimensional (3D) framework struc...

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Veröffentlicht in:Inorganic chemistry 2024-03, Vol.63 (9), p.4022-4027
Hauptverfasser: Wang, A-Yang, Ran, Mao-Yin, Wu, Xin-Tao, Lin, Hua, Zhu, Qi-Long
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container_end_page 4027
container_issue 9
container_start_page 4022
container_title Inorganic chemistry
container_volume 63
creator Wang, A-Yang
Ran, Mao-Yin
Wu, Xin-Tao
Lin, Hua
Zhu, Qi-Long
description Noncentrosymmetric (NCS) oxychalcogenides have attracted great attention in recent years due to their immense potential as candidates for IR nonlinear-optical (NLO) applications. Despite notable advancements in this field, the discovery of oxychalcogenides with three-dimensional (3D) framework structures remains a formidable challenge. In this study, we report the discovery of the first hexanary oxychalcogenide, Ba10In2Mn11Si3O12S18, exhibiting second-order NLO activity, using a high-temperature solid-phase method. This compound showcases a novel structure type, featuring an uncommon NCS 3D [In2Mn11Si3O12S18]20– framework formed by vertex-sharing [(Mn/In)­S6] octahedra, [(Mn/In)­OS3] tetrahedra, and [SiO4] tetrahedra, with charge-balanced Ba2+ cations occupying the channels. Our study serves as a source of inspiration for researchers to further investigate the synthesis of novel NLO-active oxychalcogenides with 3D frameworks.
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