Structure of Ternary Alumino-Silicate Glasses: Conditions of the Existence of Triclusters

Ternary alumino-silicate glasses, SiO2-Al2O3-(MO, M2O), contain two network former species, Si and Al. The glass structure basically consists of Si-O-Si and Si-O-Al linkages because of thermodynamically unfavorable of Al-O-Al linkage. However, Al-O-Al linkage is detected to exist as triclusters. Alt...

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Veröffentlicht in:Journal of the Ceramic Society of Japan 2004, Vol.112(1311), pp.590-593
Hauptverfasser: SIWADAMRONGPONG, Somsak, KOIDE, Manabu, MATUSITA, Kazumasa
Format: Artikel
Sprache:eng ; jpn
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