Lithiation of ramsdellite-pyrolusite MnO2; NMR, XRD, TEM and electrochemical investigation of the discharge mechanism

Electrolytic manganese dioxide (EMD) is made in aqueous sulfuric acid and neutralized or ion exchanged with aqueous lithium hydroxide before use in Li batteries. Solid state Li NMR studies show that Li is present on surface and vacancy sites and migrates into Mn (III) related sites after heat treatm...

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Veröffentlicht in:Journal of power sources 2006-02, Vol.153 (2), p.265-273
Hauptverfasser: BOWDEN, W, GREY, C. P, HACKNEY, S, WANG, F, PAIK, Y, ILTCHEV, N, SIROTINA, R
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Sprache:eng
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