Separation behaviors of actinides from rare-earths in molten salt electrorefining using saturated liquid cadmium cathode
Electrorefining in the molten LiCl–KCl eutectic salt containing actinide (An) and rare-earth (RE) elements was conducted to recover An elements up to 10 wt% into liquid cadmium (Cd) cathode, which is much higher than the solubility of the An elements in liquid Cd at the experimental temperature of 7...
Gespeichert in:
| Veröffentlicht in: | Journal of nuclear materials 2006-10, Vol.357 (1), p.105-114 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 114 |
|---|---|
| container_issue | 1 |
| container_start_page | 105 |
| container_title | Journal of nuclear materials |
| container_volume | 357 |
| creator | Kato, Tetsuya Inoue, Tadashi Iwai, Takashi Arai, Yasuo |
| description | Electrorefining in the molten LiCl–KCl eutectic salt containing actinide (An) and rare-earth (RE) elements was conducted to recover An elements up to 10
wt% into liquid cadmium (Cd) cathode, which is much higher than the solubility of the An elements in liquid Cd at the experimental temperature of 773
K. In the saturated Cd cathode, the An and RE elements were recovered forming a PuCd
11 type compound, MCd
11 (M
=
An and RE elements). The separation factors of element M against Pu defined as [M/Pu in Cd alloy (cathode)]/[M/Pu in molten salt] were calculated for the saturated Cd cathode including MCd
11. The separation factors were 0.011, 0.044, 0.064, and 0.064 for La, Ce, Pr, and Nd, respectively. These values were a little differed from 0.014, 0.038, 0.044, and 0.043 for the equilibrium unsaturated liquid Cd, respectively. The above slight differences were considered to be caused by the solid phase formation in the saturated Cd cathode and the electrochemical transfer of the An and RE elements in the molten salt. |
| doi_str_mv | 10.1016/j.jnucmat.2006.06.003 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_29318251</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0022311506003357</els_id><sourcerecordid>20246741</sourcerecordid><originalsourceid>FETCH-LOGICAL-c467t-a0ae23ef5cb47138e2653054d89e0a5c7c4146d476276137c77084b36892f8db3</originalsourceid><addsrcrecordid>eNqFkU2LFDEQhhtRcFz3Jwi56K3HylcncxJZXBUWPOieQ01S7WTo7swm6cX999vNDHhcKKouz1tfb9N84LDlwLvPx-1xmv2IdSsAuu0aIF81G26NbJUV8LrZAAjRSs712-ZdKUcA0DvQm-bfbzphxhrTxPZ0wMeYcmGpZ-hrnGKgwvqcRpYxU0uY66GwOLExDZUmVnCojAbyNadM_SKY_rK5rLlgnZe-FNgQH-YYmMcwxnlcaj2kQO-bNz0Oha4v9aq5v_325-ZHe_fr-8-br3etV52pLQKSkNRrv1eGS0ui0xK0CnZHgNobr7jqgjKdMB2XxhsDVu1lZ3eit2Evr5pP576nnB5mKtWNsXgaBpwozcWJneRWaP4yCGLZSK2gPoM-p1KWs90pxxHzk-PgVkPc0V0Mcashbg2Qi-7jZQAWj0OfcfKx_BdbbnUHauG-nDla3vIYKbviI02eQszLp11I8YVJzyDXpZU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>20246741</pqid></control><display><type>article</type><title>Separation behaviors of actinides from rare-earths in molten salt electrorefining using saturated liquid cadmium cathode</title><source>Elsevier ScienceDirect Journals</source><creator>Kato, Tetsuya ; Inoue, Tadashi ; Iwai, Takashi ; Arai, Yasuo</creator><creatorcontrib>Kato, Tetsuya ; Inoue, Tadashi ; Iwai, Takashi ; Arai, Yasuo</creatorcontrib><description>Electrorefining in the molten LiCl–KCl eutectic salt containing actinide (An) and rare-earth (RE) elements was conducted to recover An elements up to 10
wt% into liquid cadmium (Cd) cathode, which is much higher than the solubility of the An elements in liquid Cd at the experimental temperature of 773
K. In the saturated Cd cathode, the An and RE elements were recovered forming a PuCd
11 type compound, MCd
11 (M
=
An and RE elements). The separation factors of element M against Pu defined as [M/Pu in Cd alloy (cathode)]/[M/Pu in molten salt] were calculated for the saturated Cd cathode including MCd
11. The separation factors were 0.011, 0.044, 0.064, and 0.064 for La, Ce, Pr, and Nd, respectively. These values were a little differed from 0.014, 0.038, 0.044, and 0.043 for the equilibrium unsaturated liquid Cd, respectively. The above slight differences were considered to be caused by the solid phase formation in the saturated Cd cathode and the electrochemical transfer of the An and RE elements in the molten salt.</description><identifier>ISSN: 0022-3115</identifier><identifier>EISSN: 1873-4820</identifier><identifier>DOI: 10.1016/j.jnucmat.2006.06.003</identifier><identifier>CODEN: JNUMAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Energy ; Exact sciences and technology ; Fuels ; Nuclear fuels ; Preparation and processing of nuclear fuels</subject><ispartof>Journal of nuclear materials, 2006-10, Vol.357 (1), p.105-114</ispartof><rights>2006 Elsevier B.V.</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c467t-a0ae23ef5cb47138e2653054d89e0a5c7c4146d476276137c77084b36892f8db3</citedby><cites>FETCH-LOGICAL-c467t-a0ae23ef5cb47138e2653054d89e0a5c7c4146d476276137c77084b36892f8db3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0022311506003357$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18185604$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kato, Tetsuya</creatorcontrib><creatorcontrib>Inoue, Tadashi</creatorcontrib><creatorcontrib>Iwai, Takashi</creatorcontrib><creatorcontrib>Arai, Yasuo</creatorcontrib><title>Separation behaviors of actinides from rare-earths in molten salt electrorefining using saturated liquid cadmium cathode</title><title>Journal of nuclear materials</title><description>Electrorefining in the molten LiCl–KCl eutectic salt containing actinide (An) and rare-earth (RE) elements was conducted to recover An elements up to 10
wt% into liquid cadmium (Cd) cathode, which is much higher than the solubility of the An elements in liquid Cd at the experimental temperature of 773
K. In the saturated Cd cathode, the An and RE elements were recovered forming a PuCd
11 type compound, MCd
11 (M
=
An and RE elements). The separation factors of element M against Pu defined as [M/Pu in Cd alloy (cathode)]/[M/Pu in molten salt] were calculated for the saturated Cd cathode including MCd
11. The separation factors were 0.011, 0.044, 0.064, and 0.064 for La, Ce, Pr, and Nd, respectively. These values were a little differed from 0.014, 0.038, 0.044, and 0.043 for the equilibrium unsaturated liquid Cd, respectively. The above slight differences were considered to be caused by the solid phase formation in the saturated Cd cathode and the electrochemical transfer of the An and RE elements in the molten salt.</description><subject>Applied sciences</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Fuels</subject><subject>Nuclear fuels</subject><subject>Preparation and processing of nuclear fuels</subject><issn>0022-3115</issn><issn>1873-4820</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkU2LFDEQhhtRcFz3Jwi56K3HylcncxJZXBUWPOieQ01S7WTo7swm6cX999vNDHhcKKouz1tfb9N84LDlwLvPx-1xmv2IdSsAuu0aIF81G26NbJUV8LrZAAjRSs712-ZdKUcA0DvQm-bfbzphxhrTxPZ0wMeYcmGpZ-hrnGKgwvqcRpYxU0uY66GwOLExDZUmVnCojAbyNadM_SKY_rK5rLlgnZe-FNgQH-YYmMcwxnlcaj2kQO-bNz0Oha4v9aq5v_325-ZHe_fr-8-br3etV52pLQKSkNRrv1eGS0ui0xK0CnZHgNobr7jqgjKdMB2XxhsDVu1lZ3eit2Evr5pP576nnB5mKtWNsXgaBpwozcWJneRWaP4yCGLZSK2gPoM-p1KWs90pxxHzk-PgVkPc0V0Mcashbg2Qi-7jZQAWj0OfcfKx_BdbbnUHauG-nDla3vIYKbviI02eQszLp11I8YVJzyDXpZU</recordid><startdate>20061015</startdate><enddate>20061015</enddate><creator>Kato, Tetsuya</creator><creator>Inoue, Tadashi</creator><creator>Iwai, Takashi</creator><creator>Arai, Yasuo</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20061015</creationdate><title>Separation behaviors of actinides from rare-earths in molten salt electrorefining using saturated liquid cadmium cathode</title><author>Kato, Tetsuya ; Inoue, Tadashi ; Iwai, Takashi ; Arai, Yasuo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c467t-a0ae23ef5cb47138e2653054d89e0a5c7c4146d476276137c77084b36892f8db3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Fuels</topic><topic>Nuclear fuels</topic><topic>Preparation and processing of nuclear fuels</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kato, Tetsuya</creatorcontrib><creatorcontrib>Inoue, Tadashi</creatorcontrib><creatorcontrib>Iwai, Takashi</creatorcontrib><creatorcontrib>Arai, Yasuo</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of nuclear materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kato, Tetsuya</au><au>Inoue, Tadashi</au><au>Iwai, Takashi</au><au>Arai, Yasuo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Separation behaviors of actinides from rare-earths in molten salt electrorefining using saturated liquid cadmium cathode</atitle><jtitle>Journal of nuclear materials</jtitle><date>2006-10-15</date><risdate>2006</risdate><volume>357</volume><issue>1</issue><spage>105</spage><epage>114</epage><pages>105-114</pages><issn>0022-3115</issn><eissn>1873-4820</eissn><coden>JNUMAM</coden><abstract>Electrorefining in the molten LiCl–KCl eutectic salt containing actinide (An) and rare-earth (RE) elements was conducted to recover An elements up to 10
wt% into liquid cadmium (Cd) cathode, which is much higher than the solubility of the An elements in liquid Cd at the experimental temperature of 773
K. In the saturated Cd cathode, the An and RE elements were recovered forming a PuCd
11 type compound, MCd
11 (M
=
An and RE elements). The separation factors of element M against Pu defined as [M/Pu in Cd alloy (cathode)]/[M/Pu in molten salt] were calculated for the saturated Cd cathode including MCd
11. The separation factors were 0.011, 0.044, 0.064, and 0.064 for La, Ce, Pr, and Nd, respectively. These values were a little differed from 0.014, 0.038, 0.044, and 0.043 for the equilibrium unsaturated liquid Cd, respectively. The above slight differences were considered to be caused by the solid phase formation in the saturated Cd cathode and the electrochemical transfer of the An and RE elements in the molten salt.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jnucmat.2006.06.003</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-3115 |
| ispartof | Journal of nuclear materials, 2006-10, Vol.357 (1), p.105-114 |
| issn | 0022-3115 1873-4820 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_29318251 |
| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Energy Exact sciences and technology Fuels Nuclear fuels Preparation and processing of nuclear fuels |
| title | Separation behaviors of actinides from rare-earths in molten salt electrorefining using saturated liquid cadmium cathode |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T00%3A39%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Separation%20behaviors%20of%20actinides%20from%20rare-earths%20in%20molten%20salt%20electrorefining%20using%20saturated%20liquid%20cadmium%20cathode&rft.jtitle=Journal%20of%20nuclear%20materials&rft.au=Kato,%20Tetsuya&rft.date=2006-10-15&rft.volume=357&rft.issue=1&rft.spage=105&rft.epage=114&rft.pages=105-114&rft.issn=0022-3115&rft.eissn=1873-4820&rft.coden=JNUMAM&rft_id=info:doi/10.1016/j.jnucmat.2006.06.003&rft_dat=%3Cproquest_cross%3E20246741%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=20246741&rft_id=info:pmid/&rft_els_id=S0022311506003357&rfr_iscdi=true |