Plasma-sprayed graded ceramic coatings on refractory materials for improved chemical resistance

Plasma-sprayed ceramic coatings were manufactured on sintered alumina–mullite refractory bricks to improve their chemical resistance to molten glass. Mullite and alumina powders were employed. Graded layered coatings were designed and produced, to reduce the thermal expansion mismatch with the subst...

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Veröffentlicht in:Journal of the European Ceramic Society 2006, Vol.26 (13), p.2561-2579
Hauptverfasser: Bolelli, G., Cannillo, V., Lugli, C., Lusvarghi, L., Manfredini, T.
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container_end_page 2579
container_issue 13
container_start_page 2561
container_title Journal of the European Ceramic Society
container_volume 26
creator Bolelli, G.
Cannillo, V.
Lugli, C.
Lusvarghi, L.
Manfredini, T.
description Plasma-sprayed ceramic coatings were manufactured on sintered alumina–mullite refractory bricks to improve their chemical resistance to molten glass. Mullite and alumina powders were employed. Graded layered coatings were designed and produced, to reduce the thermal expansion mismatch with the substrate: in all cases, the upper layer consisted in pure alumina (very resistant to chemical attack); alumina–mullite intermediate layers were added to match the low thermal expansion of the porous substrates. Plasma-sprayed coatings definitely improved both the abrasion resistance and the chemical resistance to long-time (8 h at 1400 °C) contact with molten glass, since the coating preserved its original microstructure. However, in thermal shock tests, some transverse cracks appeared; thus, thermal cycling tests in presence of molten glass indicated that, after a few cycles, the glass can penetrate down to these cracks. The tested samples were studied by means of scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS) and X-ray diffraction (XRD).
doi_str_mv 10.1016/j.jeurceramsoc.2005.07.066
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source Elsevier ScienceDirect Journals
subjects Applied sciences
Building materials. Ceramics. Glasses
Ceramic industries
Chemical industry and chemicals
Chemical properties
Coatings
Exact sciences and technology
Miscellaneous
Plasma spraying
Refractories
Refractory products
Silica-alumina refractories
Technical ceramics
Thermal shock resistance
Wear resistance
title Plasma-sprayed graded ceramic coatings on refractory materials for improved chemical resistance
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