Pyrolitic carbon from biomass precursors as anode materials for lithium batteries
Disordered carbonaceous materials were synthesized by the pyrolysis of banana fibers treated with pore-forming substances such as ZnCl 2 and KOH. X-ray diffraction studies indicated a carbon structure with a large number of disorganized single layer carbon sheets. Addition of porogenic agent led to...
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| Veröffentlicht in: | Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 2006-08, Vol.430 (1), p.132-137 |
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| container_issue | 1 |
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| container_title | Materials science & engineering. A, Structural materials : properties, microstructure and processing |
| container_volume | 430 |
| creator | Stephan, A. Manuel Kumar, T. Prem Ramesh, R. Thomas, Sabu Jeong, Soo Kyung Nahm, Kee Suk |
| description | Disordered carbonaceous materials were synthesized by the pyrolysis of banana fibers treated with pore-forming substances such as ZnCl
2 and KOH. X-ray diffraction studies indicated a carbon structure with a large number of disorganized single layer carbon sheets. Addition of porogenic agent led to remarkable changes in the structure and morphology of the carbonaceous products. The product obtained with ZnCl
2 treatment gave first-cycle lithium insertion and de-insertion capacities of 3325 and 400
mAh
g
−1, respectively. Lower capacities only could be realized in the subsequent cycles, although the coulombic efficiency increased upon cycling, which in the 10th cycle was 95%. |
| doi_str_mv | 10.1016/j.msea.2006.05.131 |
| format | Article |
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2 and KOH. X-ray diffraction studies indicated a carbon structure with a large number of disorganized single layer carbon sheets. Addition of porogenic agent led to remarkable changes in the structure and morphology of the carbonaceous products. The product obtained with ZnCl
2 treatment gave first-cycle lithium insertion and de-insertion capacities of 3325 and 400
mAh
g
−1, respectively. Lower capacities only could be realized in the subsequent cycles, although the coulombic efficiency increased upon cycling, which in the 10th cycle was 95%.</description><identifier>ISSN: 0921-5093</identifier><identifier>EISSN: 1873-4936</identifier><identifier>DOI: 10.1016/j.msea.2006.05.131</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Banana fiber ; Carbon anode ; Energy ; Energy. Thermal use of fuels ; Exact sciences and technology ; Lithium-ion battery ; Porogen ; Pyrolytic carbon ; Transport and storage of energy</subject><ispartof>Materials science & engineering. A, Structural materials : properties, microstructure and processing, 2006-08, Vol.430 (1), p.132-137</ispartof><rights>2006 Elsevier B.V.</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-974c2a41ca1c783d9fb4ee653ba699b95c62e27ab5b051977b119f4c4bb67d4e3</citedby><cites>FETCH-LOGICAL-c361t-974c2a41ca1c783d9fb4ee653ba699b95c62e27ab5b051977b119f4c4bb67d4e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0921509306008690$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17993835$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Stephan, A. Manuel</creatorcontrib><creatorcontrib>Kumar, T. Prem</creatorcontrib><creatorcontrib>Ramesh, R.</creatorcontrib><creatorcontrib>Thomas, Sabu</creatorcontrib><creatorcontrib>Jeong, Soo Kyung</creatorcontrib><creatorcontrib>Nahm, Kee Suk</creatorcontrib><title>Pyrolitic carbon from biomass precursors as anode materials for lithium batteries</title><title>Materials science & engineering. A, Structural materials : properties, microstructure and processing</title><description>Disordered carbonaceous materials were synthesized by the pyrolysis of banana fibers treated with pore-forming substances such as ZnCl
2 and KOH. X-ray diffraction studies indicated a carbon structure with a large number of disorganized single layer carbon sheets. Addition of porogenic agent led to remarkable changes in the structure and morphology of the carbonaceous products. The product obtained with ZnCl
2 treatment gave first-cycle lithium insertion and de-insertion capacities of 3325 and 400
mAh
g
−1, respectively. Lower capacities only could be realized in the subsequent cycles, although the coulombic efficiency increased upon cycling, which in the 10th cycle was 95%.</description><subject>Applied sciences</subject><subject>Banana fiber</subject><subject>Carbon anode</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Exact sciences and technology</subject><subject>Lithium-ion battery</subject><subject>Porogen</subject><subject>Pyrolytic carbon</subject><subject>Transport and storage of energy</subject><issn>0921-5093</issn><issn>1873-4936</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouH78AU-96K010zTtBrzI4hcsqKDnkKRTzNI2a6Yr-O_NugvehIGBmfd5h3kZuwBeAIf6elUMhKYoOa8LLgsQcMBmMG9EXilRH7IZVyXkkitxzE6IVpxzqLicsdeX7xh6P3mXORNtGLMuhiGzPgyGKFtHdJtIIVJmUo2hxWwwE0Zvesq6ELPEfvhNIsy0HSOdsaMuLfF830_Z-_3d2-IxXz4_PC1ul7kTNUy5aipXmgqcAdfMRas6WyHWUlhTK2WVdHWJZWOstFyCahoLoLrKVdbWTVuhOGVXO991DJ8bpEkPnhz2vRkxbEiXqkyUgCQsd0IXA1HETq-jH0z81sD1Nj290tv09DY9zaWGX-hy727Imb6LZnSe_shGKTEXMuludjpMr355jJqcx9Fh61N0k26D_-_MDxqUhsc</recordid><startdate>20060825</startdate><enddate>20060825</enddate><creator>Stephan, A. Manuel</creator><creator>Kumar, T. Prem</creator><creator>Ramesh, R.</creator><creator>Thomas, Sabu</creator><creator>Jeong, Soo Kyung</creator><creator>Nahm, Kee Suk</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20060825</creationdate><title>Pyrolitic carbon from biomass precursors as anode materials for lithium batteries</title><author>Stephan, A. Manuel ; Kumar, T. Prem ; Ramesh, R. ; Thomas, Sabu ; Jeong, Soo Kyung ; Nahm, Kee Suk</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-974c2a41ca1c783d9fb4ee653ba699b95c62e27ab5b051977b119f4c4bb67d4e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Banana fiber</topic><topic>Carbon anode</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Exact sciences and technology</topic><topic>Lithium-ion battery</topic><topic>Porogen</topic><topic>Pyrolytic carbon</topic><topic>Transport and storage of energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stephan, A. Manuel</creatorcontrib><creatorcontrib>Kumar, T. Prem</creatorcontrib><creatorcontrib>Ramesh, R.</creatorcontrib><creatorcontrib>Thomas, Sabu</creatorcontrib><creatorcontrib>Jeong, Soo Kyung</creatorcontrib><creatorcontrib>Nahm, Kee Suk</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials science & engineering. A, Structural materials : properties, microstructure and processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stephan, A. Manuel</au><au>Kumar, T. Prem</au><au>Ramesh, R.</au><au>Thomas, Sabu</au><au>Jeong, Soo Kyung</au><au>Nahm, Kee Suk</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pyrolitic carbon from biomass precursors as anode materials for lithium batteries</atitle><jtitle>Materials science & engineering. A, Structural materials : properties, microstructure and processing</jtitle><date>2006-08-25</date><risdate>2006</risdate><volume>430</volume><issue>1</issue><spage>132</spage><epage>137</epage><pages>132-137</pages><issn>0921-5093</issn><eissn>1873-4936</eissn><abstract>Disordered carbonaceous materials were synthesized by the pyrolysis of banana fibers treated with pore-forming substances such as ZnCl
2 and KOH. X-ray diffraction studies indicated a carbon structure with a large number of disorganized single layer carbon sheets. Addition of porogenic agent led to remarkable changes in the structure and morphology of the carbonaceous products. The product obtained with ZnCl
2 treatment gave first-cycle lithium insertion and de-insertion capacities of 3325 and 400
mAh
g
−1, respectively. Lower capacities only could be realized in the subsequent cycles, although the coulombic efficiency increased upon cycling, which in the 10th cycle was 95%.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.msea.2006.05.131</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0921-5093 |
| ispartof | Materials science & engineering. A, Structural materials : properties, microstructure and processing, 2006-08, Vol.430 (1), p.132-137 |
| issn | 0921-5093 1873-4936 |
| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Applied sciences Banana fiber Carbon anode Energy Energy. Thermal use of fuels Exact sciences and technology Lithium-ion battery Porogen Pyrolytic carbon Transport and storage of energy |
| title | Pyrolitic carbon from biomass precursors as anode materials for lithium batteries |
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