A dinuclear CdII cluster-based stable luminescent metal–organic framework for the consecutive and visual detection of H2PO4− and OCN
Due to their hazard to biological systems, it is urgent to develop materials that can rapidly and sensitively detect the concentration of H2PO4− and OCN− ions. In this work, a new CdII-based luminescent metal–organic framework with the formula [Cd(BTDB)(2,6-BBIP)]n (JXUST-47, H2BTDB = (benzo[c][1,2,...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-03, Vol.53 (11), p.5160-5166 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Lu, Na Wang, Li Teng-Fei, Zheng Peng, Yan Sui-Jun, Liu He-Rui, Wen |
| description | Due to their hazard to biological systems, it is urgent to develop materials that can rapidly and sensitively detect the concentration of H2PO4− and OCN− ions. In this work, a new CdII-based luminescent metal–organic framework with the formula [Cd(BTDB)(2,6-BBIP)]n (JXUST-47, H2BTDB = (benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid, 2,6-BBIP = 2,6-bis(benzimidazol-1-yl)pyridine) and sql topology was successfully synthesized using a mixed-ligand strategy. JXUST-47 shows good chemical and thermal stability. It also exhibits weak quenching and fluorescence blue shift for H2PO4− and red shift for OCN−, with the detection limits of 0.106 and 0.128 mM, respectively. In addition, considering the demand for H2PO4− and OCN− ion detection, by combining this with the functions of a smartphone, the chroma of photographs have been used to realize the consecutive visual detection of the concentration of these ions. |
| doi_str_mv | 10.1039/d3dt03523a |
| format | Article |
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In this work, a new CdII-based luminescent metal–organic framework with the formula [Cd(BTDB)(2,6-BBIP)]n (JXUST-47, H2BTDB = (benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid, 2,6-BBIP = 2,6-bis(benzimidazol-1-yl)pyridine) and sql topology was successfully synthesized using a mixed-ligand strategy. JXUST-47 shows good chemical and thermal stability. It also exhibits weak quenching and fluorescence blue shift for H2PO4− and red shift for OCN−, with the detection limits of 0.106 and 0.128 mM, respectively. In addition, considering the demand for H2PO4− and OCN− ion detection, by combining this with the functions of a smartphone, the chroma of photographs have been used to realize the consecutive visual detection of the concentration of these ions.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt03523a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Blue shift ; Doppler effect ; Metal-organic frameworks ; Red shift ; Thermal stability ; Thiadiazoles ; Topology</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-03, Vol.53 (11), p.5160-5166</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Lu, Na</creatorcontrib><creatorcontrib>Wang, Li</creatorcontrib><creatorcontrib>Teng-Fei, Zheng</creatorcontrib><creatorcontrib>Peng, Yan</creatorcontrib><creatorcontrib>Sui-Jun, Liu</creatorcontrib><creatorcontrib>He-Rui, Wen</creatorcontrib><title>A dinuclear CdII cluster-based stable luminescent metal–organic framework for the consecutive and visual detection of H2PO4− and OCN</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Due to their hazard to biological systems, it is urgent to develop materials that can rapidly and sensitively detect the concentration of H2PO4− and OCN− ions. In this work, a new CdII-based luminescent metal–organic framework with the formula [Cd(BTDB)(2,6-BBIP)]n (JXUST-47, H2BTDB = (benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid, 2,6-BBIP = 2,6-bis(benzimidazol-1-yl)pyridine) and sql topology was successfully synthesized using a mixed-ligand strategy. JXUST-47 shows good chemical and thermal stability. It also exhibits weak quenching and fluorescence blue shift for H2PO4− and red shift for OCN−, with the detection limits of 0.106 and 0.128 mM, respectively. In addition, considering the demand for H2PO4− and OCN− ion detection, by combining this with the functions of a smartphone, the chroma of photographs have been used to realize the consecutive visual detection of the concentration of these ions.</description><subject>Blue shift</subject><subject>Doppler effect</subject><subject>Metal-organic frameworks</subject><subject>Red shift</subject><subject>Thermal stability</subject><subject>Thiadiazoles</subject><subject>Topology</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpdkL1OwzAcxCMEEqWw8ASWWFgC_ozxWEVAK1WUAebKsf-BFMcusQMrY2d4wz4J4UMMTHfDT6e7y7Jjgs8IZurcMpswE5TpnWxEuJS5oozv_nla7GcHMa4wphQLOso2E2Qb3xsHukOlnc2QcX1M0OWVjmBRTLpygFzfNh6iAZ9QC0m77dtH6B60bwyqO93Ca-ieUB06lB4BmeAjmD41L4C0t-ilib12yEICk5rgUajRlN4u-Hbz_g0sypvDbK_WLsLRr46z-6vLu3KazxfXs3Iyz9eEFykHKYESS4mGi4pzXivBFCMUm6JmEluqqCqowEIopo2URNHKKmKgljXXlWbj7PQnd92F5x5iWrbNsMs57SH0cfkVIDgmTA7oyT90FfrOD-0GSgg6PC4V-wS-l3NX</recordid><startdate>20240312</startdate><enddate>20240312</enddate><creator>Lu, Na</creator><creator>Wang, Li</creator><creator>Teng-Fei, Zheng</creator><creator>Peng, Yan</creator><creator>Sui-Jun, Liu</creator><creator>He-Rui, Wen</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20240312</creationdate><title>A dinuclear CdII cluster-based stable luminescent metal–organic framework for the consecutive and visual detection of H2PO4− and OCN</title><author>Lu, Na ; Wang, Li ; Teng-Fei, Zheng ; Peng, Yan ; Sui-Jun, Liu ; He-Rui, Wen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p146t-e77e21d21ae8b444f95393120c6f370d292962505593ac77192bd91cef7f4aba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Blue shift</topic><topic>Doppler effect</topic><topic>Metal-organic frameworks</topic><topic>Red shift</topic><topic>Thermal stability</topic><topic>Thiadiazoles</topic><topic>Topology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lu, Na</creatorcontrib><creatorcontrib>Wang, Li</creatorcontrib><creatorcontrib>Teng-Fei, Zheng</creatorcontrib><creatorcontrib>Peng, Yan</creatorcontrib><creatorcontrib>Sui-Jun, Liu</creatorcontrib><creatorcontrib>He-Rui, Wen</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lu, Na</au><au>Wang, Li</au><au>Teng-Fei, Zheng</au><au>Peng, Yan</au><au>Sui-Jun, Liu</au><au>He-Rui, Wen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A dinuclear CdII cluster-based stable luminescent metal–organic framework for the consecutive and visual detection of H2PO4− and OCN</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2024-03-12</date><risdate>2024</risdate><volume>53</volume><issue>11</issue><spage>5160</spage><epage>5166</epage><pages>5160-5166</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Due to their hazard to biological systems, it is urgent to develop materials that can rapidly and sensitively detect the concentration of H2PO4− and OCN− ions. In this work, a new CdII-based luminescent metal–organic framework with the formula [Cd(BTDB)(2,6-BBIP)]n (JXUST-47, H2BTDB = (benzo[c][1,2,5]thiadiazole-4,7-diyl)dibenzoic acid, 2,6-BBIP = 2,6-bis(benzimidazol-1-yl)pyridine) and sql topology was successfully synthesized using a mixed-ligand strategy. JXUST-47 shows good chemical and thermal stability. It also exhibits weak quenching and fluorescence blue shift for H2PO4− and red shift for OCN−, with the detection limits of 0.106 and 0.128 mM, respectively. In addition, considering the demand for H2PO4− and OCN− ion detection, by combining this with the functions of a smartphone, the chroma of photographs have been used to realize the consecutive visual detection of the concentration of these ions.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3dt03523a</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2024-03, Vol.53 (11), p.5160-5166 |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Blue shift Doppler effect Metal-organic frameworks Red shift Thermal stability Thiadiazoles Topology |
| title | A dinuclear CdII cluster-based stable luminescent metal–organic framework for the consecutive and visual detection of H2PO4− and OCN |
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