Self-Assembly of Functionalized Twistarenes into Supramolecular Assemblies with Chiroptical Property and Photoconductive Behavior

Self-Assembly of Functionalized Twistarenes into Supramolecular Assemblies with Chiroptical Property and Photoconductive Behavior

A pair of novel chiral 1-phenylethylamine-modified twistarenes (4 and 11; compound 4 = 9,14-di-tert-butyl-7,16-diphenyl-2-(1-phenylethyl)-1H-benzo­[8',9']­triphenyleno­[2',3':6,7]­fluoreno­[2,1,9-def]­isoquinoline-1,3­(2H)-dione) have been synthesized and characterized, and how t...

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Veröffentlicht in:Organic letters 2024-02, Vol.26 (4), p.781-785
Hauptverfasser: Qi, Zewei, Wang, Sujuan, Ji, Bingliang, Shang, Honglin, Ye, Tongtong, Shi, Yanwei, Xiao, Jinchong
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container_end_page 785
container_issue 4
container_start_page 781
container_title Organic letters
container_volume 26
creator Qi, Zewei
Wang, Sujuan
Ji, Bingliang
Shang, Honglin
Ye, Tongtong
Shi, Yanwei
Xiao, Jinchong
description A pair of novel chiral 1-phenylethylamine-modified twistarenes (4 and 11; compound 4 = 9,14-di-tert-butyl-7,16-diphenyl-2-(1-phenylethyl)-1H-benzo­[8',9']­triphenyleno­[2',3':6,7]­fluoreno­[2,1,9-def]­isoquinoline-1,3­(2H)-dione) have been synthesized and characterized, and how the solvent component affects the chirality transfer of their self-assembled processes is investigated in mixtures with THF and H2O. The ordered assembly of 11 exhibits circular dichroism response. In addition, both 11a and 11b display positive photoconducting behavior.
doi_str_mv 10.1021/acs.orglett.3c03854
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title Self-Assembly of Functionalized Twistarenes into Supramolecular Assemblies with Chiroptical Property and Photoconductive Behavior
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