A Boron Scan of Ethyl Acetoacetate Leads to Versatile Building Blocks

Discovered in the 19th century, ethyl acetoacetate has been central to the development of organic chemistry, including its pedagogy and applications. In this study, we present borylated derivatives of this venerable molecule. A boron handle has been installed at either α ${{\rm \alpha }}$ ‐ or β ${\...

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Veröffentlicht in:	Angewandte Chemie International Edition 2024-04, Vol.63 (15), p.e202319842-n/a
Hauptverfasser:	Trofimova, Alina, White, Brandon, Diaz, Diego B., Širvinskas, Martynas J., Lough, Alan, Dudding, Travis, Yudin, Andrei K.
Format:	Artikel
Sprache:	eng
Schlagworte:	acetoacetate acylboronate Boron heterocycles homologation Ketoesters Organic chemistry Oximes regioselectivity
Online-Zugang:	Volltext
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