Ecotoxic effect in Allium cepa due to sphalerite weathering arising in calcareous conditions
The ecotoxic effect of Zn species arising from the weathering of the marmatite-like sphalerite ((Fe, Zn)S) in Allium cepa systems was herein evaluated in calcareous soils and connected with its sulfide oxidation mechanism to determine the chemical speciation responsible of this outcome. Mineralogica...
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| Veröffentlicht in: | Environmental geochemistry and health 2024-03, Vol.46 (3), p.87-87, Article 87 |
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| creator | Ponce-Peña, Patricia López-Ortega, Aldo R. Anguiano-Vega, Gerardo A. Sosa-Rodríguez, Fabiola S. Vázquez-Arenas, Jorge Ramírez-Aldaba, Hugo González-Lozano, Ma. Azucena Trejo, Gabriel Ruiz-Baca, Estela Labastida, Israel Escobedo-Bretado, Miguel A. Lara, René H. |
| description | The ecotoxic effect of Zn species arising from the weathering of the marmatite-like sphalerite ((Fe, Zn)S) in
Allium cepa
systems was herein evaluated in calcareous soils and connected with its sulfide oxidation mechanism to determine the chemical speciation responsible of this outcome. Mineralogical analyses (X-ray diffraction patterns, Raman spectroscopy, scanning electron microscopy and atomic force microscopy), chemical study of leachates (total Fe, Zn, Cd, oxidation–reduction potential, pH, sulfates and total alkalinity) and electrochemical assessments (chronoamperometry, chronopotentiometry, cyclic voltammetry, and electrochemical impedance spectroscopy) were carried out using (Fe, Zn)S samples to elucidate interfacial mechanisms simulating calcareous soil conditions. Results indicate the formation of polysulfides (S
n
2−
), elemental sulfur (S
0
), siderite (FeCO
3
)-like, hematite (Fe
2
O
3
)-like with sorbed CO
3
2−
species, gunningite (ZnSO
4
·H
2
O)-like phase and smithsonite (ZnCO
3
)-like compounds in altered surface under calcareous conditions. However, the generation of gunningite (ZnSO
4
·H
2
O)-like phase was predominant bulk-solution system. Quantification of damage rates ranges from 75 to 90% of bulb cells under non-carbonated conditions after 15–30 days, while 50–75% of damage level is determined under neutral-alkaline carbonated conditions. Damage ratios are 70.08 and 30.26 at the highest level, respectively. These findings revealed lower ecotoxic damage due to ZnCO
3
-like precipitation, indicating the effect of carbonates on Zn compounds during vegetable up-taking (exposure). Other environmental suggestions of the (Fe, Zn)S weathering and ecotoxic effects under calcareous soil conditions are discussed. |
| doi_str_mv | 10.1007/s10653-024-01857-z |
| format | Article |
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Allium cepa
systems was herein evaluated in calcareous soils and connected with its sulfide oxidation mechanism to determine the chemical speciation responsible of this outcome. Mineralogical analyses (X-ray diffraction patterns, Raman spectroscopy, scanning electron microscopy and atomic force microscopy), chemical study of leachates (total Fe, Zn, Cd, oxidation–reduction potential, pH, sulfates and total alkalinity) and electrochemical assessments (chronoamperometry, chronopotentiometry, cyclic voltammetry, and electrochemical impedance spectroscopy) were carried out using (Fe, Zn)S samples to elucidate interfacial mechanisms simulating calcareous soil conditions. Results indicate the formation of polysulfides (S
n
2−
), elemental sulfur (S
0
), siderite (FeCO
3
)-like, hematite (Fe
2
O
3
)-like with sorbed CO
3
2−
species, gunningite (ZnSO
4
·H
2
O)-like phase and smithsonite (ZnCO
3
)-like compounds in altered surface under calcareous conditions. However, the generation of gunningite (ZnSO
4
·H
2
O)-like phase was predominant bulk-solution system. Quantification of damage rates ranges from 75 to 90% of bulb cells under non-carbonated conditions after 15–30 days, while 50–75% of damage level is determined under neutral-alkaline carbonated conditions. Damage ratios are 70.08 and 30.26 at the highest level, respectively. These findings revealed lower ecotoxic damage due to ZnCO
3
-like precipitation, indicating the effect of carbonates on Zn compounds during vegetable up-taking (exposure). Other environmental suggestions of the (Fe, Zn)S weathering and ecotoxic effects under calcareous soil conditions are discussed.</description><identifier>ISSN: 0269-4042</identifier><identifier>EISSN: 1573-2983</identifier><identifier>DOI: 10.1007/s10653-024-01857-z</identifier><identifier>PMID: 38367090</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Alkalinity ; Allium cepa ; Analytical methods ; Atomic force microscopy ; bulbs ; Calcareous soils ; Carbonates ; Carbonation ; Chemical speciation ; Damage ; dielectric spectroscopy ; Diffraction patterns ; Earth and Environmental Science ; Electrochemical impedance spectroscopy ; Electrochemistry ; Electron microscopy ; Environment ; Environmental Chemistry ; Environmental Health ; Ferric oxide ; Geochemistry ; Haematite ; Hematite ; Iron ; Iron carbonate ; Leachates ; Microscopy ; Original Paper ; Oxidation ; Public Health ; Raman spectroscopy ; redox potential ; Scanning electron microscopy ; Siderite ; smithsonite ; Soil ; Soil conditions ; Soil Science & Conservation ; Speciation ; species ; Spectroscopy ; Spectrum analysis ; Sphalerite ; sulfides ; Sulfur ; Sulphides ; Sulphur ; Terrestrial Pollution ; vegetables ; voltammetry ; Weathering ; X-ray diffraction ; Zinc ; Zinc ores ; Zinc sulfate ; Zincblende</subject><ispartof>Environmental geochemistry and health, 2024-03, Vol.46 (3), p.87-87, Article 87</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2024. The Author(s), under exclusive licence to Springer Nature B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c359t-a2c087e8e219a625587105172dd44c1277ff942f776b8d02e6f5a13e7d62dd973</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10653-024-01857-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10653-024-01857-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38367090$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ponce-Peña, Patricia</creatorcontrib><creatorcontrib>López-Ortega, Aldo R.</creatorcontrib><creatorcontrib>Anguiano-Vega, Gerardo A.</creatorcontrib><creatorcontrib>Sosa-Rodríguez, Fabiola S.</creatorcontrib><creatorcontrib>Vázquez-Arenas, Jorge</creatorcontrib><creatorcontrib>Ramírez-Aldaba, Hugo</creatorcontrib><creatorcontrib>González-Lozano, Ma. Azucena</creatorcontrib><creatorcontrib>Trejo, Gabriel</creatorcontrib><creatorcontrib>Ruiz-Baca, Estela</creatorcontrib><creatorcontrib>Labastida, Israel</creatorcontrib><creatorcontrib>Escobedo-Bretado, Miguel A.</creatorcontrib><creatorcontrib>Lara, René H.</creatorcontrib><title>Ecotoxic effect in Allium cepa due to sphalerite weathering arising in calcareous conditions</title><title>Environmental geochemistry and health</title><addtitle>Environ Geochem Health</addtitle><addtitle>Environ Geochem Health</addtitle><description>The ecotoxic effect of Zn species arising from the weathering of the marmatite-like sphalerite ((Fe, Zn)S) in
Allium cepa
systems was herein evaluated in calcareous soils and connected with its sulfide oxidation mechanism to determine the chemical speciation responsible of this outcome. Mineralogical analyses (X-ray diffraction patterns, Raman spectroscopy, scanning electron microscopy and atomic force microscopy), chemical study of leachates (total Fe, Zn, Cd, oxidation–reduction potential, pH, sulfates and total alkalinity) and electrochemical assessments (chronoamperometry, chronopotentiometry, cyclic voltammetry, and electrochemical impedance spectroscopy) were carried out using (Fe, Zn)S samples to elucidate interfacial mechanisms simulating calcareous soil conditions. Results indicate the formation of polysulfides (S
n
2−
), elemental sulfur (S
0
), siderite (FeCO
3
)-like, hematite (Fe
2
O
3
)-like with sorbed CO
3
2−
species, gunningite (ZnSO
4
·H
2
O)-like phase and smithsonite (ZnCO
3
)-like compounds in altered surface under calcareous conditions. However, the generation of gunningite (ZnSO
4
·H
2
O)-like phase was predominant bulk-solution system. Quantification of damage rates ranges from 75 to 90% of bulb cells under non-carbonated conditions after 15–30 days, while 50–75% of damage level is determined under neutral-alkaline carbonated conditions. Damage ratios are 70.08 and 30.26 at the highest level, respectively. These findings revealed lower ecotoxic damage due to ZnCO
3
-like precipitation, indicating the effect of carbonates on Zn compounds during vegetable up-taking (exposure). Other environmental suggestions of the (Fe, Zn)S weathering and ecotoxic effects under calcareous soil conditions are discussed.</description><subject>Alkalinity</subject><subject>Allium cepa</subject><subject>Analytical methods</subject><subject>Atomic force microscopy</subject><subject>bulbs</subject><subject>Calcareous soils</subject><subject>Carbonates</subject><subject>Carbonation</subject><subject>Chemical speciation</subject><subject>Damage</subject><subject>dielectric spectroscopy</subject><subject>Diffraction patterns</subject><subject>Earth and Environmental Science</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Electron microscopy</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Ferric oxide</subject><subject>Geochemistry</subject><subject>Haematite</subject><subject>Hematite</subject><subject>Iron</subject><subject>Iron carbonate</subject><subject>Leachates</subject><subject>Microscopy</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Public Health</subject><subject>Raman spectroscopy</subject><subject>redox potential</subject><subject>Scanning electron microscopy</subject><subject>Siderite</subject><subject>smithsonite</subject><subject>Soil</subject><subject>Soil conditions</subject><subject>Soil Science & Conservation</subject><subject>Speciation</subject><subject>species</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Sphalerite</subject><subject>sulfides</subject><subject>Sulfur</subject><subject>Sulphides</subject><subject>Sulphur</subject><subject>Terrestrial Pollution</subject><subject>vegetables</subject><subject>voltammetry</subject><subject>Weathering</subject><subject>X-ray diffraction</subject><subject>Zinc</subject><subject>Zinc ores</subject><subject>Zinc sulfate</subject><subject>Zincblende</subject><issn>0269-4042</issn><issn>1573-2983</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkctO3TAURa0KVG6hP9BBZYlJJ2mP7fg1RIg-JKROygzJMs5JMcqNg52Ix9fX6aWtxICOjgdrb_t4EfKOwUcGoD8VBkqKBnjbADNSN4-vyIZJLRpujdgjG-DKNi20_IC8KeUGAKxuzWtyIIxQGixsyOVZSHO6j4Fi32OYaRzpyTDEZUsDTp52C9I50TJd-wFznJHeoZ-v63H8SX2OZZ01E_wQfMa0FBrS2MU5prEckf3eDwXfPs1DcvH57Mfp1-b8-5dvpyfnTRDSzo3nAYxGg5xZr7iURjOQTPOua9vAuNZ9b1vea62uTAccVS89E6g7VRGrxSH5sOudcrpdsMxuG0vAYfDj-iInmBTSKK34f1FuueESlGUVPX6G3qQlj3WRldLGsNaKSvEdFXIqJWPvphy3Pj84Bm7V5HaaXNXkfmtyjzX0_ql6udpi9zfyx0sFxA4o0_rTmP_d_ULtL-xBnOQ</recordid><startdate>20240301</startdate><enddate>20240301</enddate><creator>Ponce-Peña, Patricia</creator><creator>López-Ortega, Aldo R.</creator><creator>Anguiano-Vega, Gerardo A.</creator><creator>Sosa-Rodríguez, Fabiola S.</creator><creator>Vázquez-Arenas, Jorge</creator><creator>Ramírez-Aldaba, Hugo</creator><creator>González-Lozano, Ma. Azucena</creator><creator>Trejo, Gabriel</creator><creator>Ruiz-Baca, Estela</creator><creator>Labastida, Israel</creator><creator>Escobedo-Bretado, Miguel A.</creator><creator>Lara, René H.</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>K9.</scope><scope>L.G</scope><scope>SOI</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20240301</creationdate><title>Ecotoxic effect in Allium cepa due to sphalerite weathering arising in calcareous conditions</title><author>Ponce-Peña, Patricia ; López-Ortega, Aldo R. ; Anguiano-Vega, Gerardo A. ; Sosa-Rodríguez, Fabiola S. ; Vázquez-Arenas, Jorge ; Ramírez-Aldaba, Hugo ; González-Lozano, Ma. Azucena ; Trejo, Gabriel ; Ruiz-Baca, Estela ; Labastida, Israel ; Escobedo-Bretado, Miguel A. ; Lara, René H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-a2c087e8e219a625587105172dd44c1277ff942f776b8d02e6f5a13e7d62dd973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Alkalinity</topic><topic>Allium cepa</topic><topic>Analytical methods</topic><topic>Atomic force microscopy</topic><topic>bulbs</topic><topic>Calcareous soils</topic><topic>Carbonates</topic><topic>Carbonation</topic><topic>Chemical speciation</topic><topic>Damage</topic><topic>dielectric spectroscopy</topic><topic>Diffraction patterns</topic><topic>Earth and Environmental Science</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Electron microscopy</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Ferric oxide</topic><topic>Geochemistry</topic><topic>Haematite</topic><topic>Hematite</topic><topic>Iron</topic><topic>Iron carbonate</topic><topic>Leachates</topic><topic>Microscopy</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Public Health</topic><topic>Raman spectroscopy</topic><topic>redox potential</topic><topic>Scanning electron microscopy</topic><topic>Siderite</topic><topic>smithsonite</topic><topic>Soil</topic><topic>Soil conditions</topic><topic>Soil Science & Conservation</topic><topic>Speciation</topic><topic>species</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><topic>Sphalerite</topic><topic>sulfides</topic><topic>Sulfur</topic><topic>Sulphides</topic><topic>Sulphur</topic><topic>Terrestrial Pollution</topic><topic>vegetables</topic><topic>voltammetry</topic><topic>Weathering</topic><topic>X-ray diffraction</topic><topic>Zinc</topic><topic>Zinc ores</topic><topic>Zinc sulfate</topic><topic>Zincblende</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ponce-Peña, Patricia</creatorcontrib><creatorcontrib>López-Ortega, Aldo R.</creatorcontrib><creatorcontrib>Anguiano-Vega, Gerardo A.</creatorcontrib><creatorcontrib>Sosa-Rodríguez, Fabiola S.</creatorcontrib><creatorcontrib>Vázquez-Arenas, Jorge</creatorcontrib><creatorcontrib>Ramírez-Aldaba, Hugo</creatorcontrib><creatorcontrib>González-Lozano, Ma. Azucena</creatorcontrib><creatorcontrib>Trejo, Gabriel</creatorcontrib><creatorcontrib>Ruiz-Baca, Estela</creatorcontrib><creatorcontrib>Labastida, Israel</creatorcontrib><creatorcontrib>Escobedo-Bretado, Miguel A.</creatorcontrib><creatorcontrib>Lara, René H.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Environment Abstracts</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Environmental geochemistry and health</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ponce-Peña, Patricia</au><au>López-Ortega, Aldo R.</au><au>Anguiano-Vega, Gerardo A.</au><au>Sosa-Rodríguez, Fabiola S.</au><au>Vázquez-Arenas, Jorge</au><au>Ramírez-Aldaba, Hugo</au><au>González-Lozano, Ma. Azucena</au><au>Trejo, Gabriel</au><au>Ruiz-Baca, Estela</au><au>Labastida, Israel</au><au>Escobedo-Bretado, Miguel A.</au><au>Lara, René H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ecotoxic effect in Allium cepa due to sphalerite weathering arising in calcareous conditions</atitle><jtitle>Environmental geochemistry and health</jtitle><stitle>Environ Geochem Health</stitle><addtitle>Environ Geochem Health</addtitle><date>2024-03-01</date><risdate>2024</risdate><volume>46</volume><issue>3</issue><spage>87</spage><epage>87</epage><pages>87-87</pages><artnum>87</artnum><issn>0269-4042</issn><eissn>1573-2983</eissn><abstract>The ecotoxic effect of Zn species arising from the weathering of the marmatite-like sphalerite ((Fe, Zn)S) in
Allium cepa
systems was herein evaluated in calcareous soils and connected with its sulfide oxidation mechanism to determine the chemical speciation responsible of this outcome. Mineralogical analyses (X-ray diffraction patterns, Raman spectroscopy, scanning electron microscopy and atomic force microscopy), chemical study of leachates (total Fe, Zn, Cd, oxidation–reduction potential, pH, sulfates and total alkalinity) and electrochemical assessments (chronoamperometry, chronopotentiometry, cyclic voltammetry, and electrochemical impedance spectroscopy) were carried out using (Fe, Zn)S samples to elucidate interfacial mechanisms simulating calcareous soil conditions. Results indicate the formation of polysulfides (S
n
2−
), elemental sulfur (S
0
), siderite (FeCO
3
)-like, hematite (Fe
2
O
3
)-like with sorbed CO
3
2−
species, gunningite (ZnSO
4
·H
2
O)-like phase and smithsonite (ZnCO
3
)-like compounds in altered surface under calcareous conditions. However, the generation of gunningite (ZnSO
4
·H
2
O)-like phase was predominant bulk-solution system. Quantification of damage rates ranges from 75 to 90% of bulb cells under non-carbonated conditions after 15–30 days, while 50–75% of damage level is determined under neutral-alkaline carbonated conditions. Damage ratios are 70.08 and 30.26 at the highest level, respectively. These findings revealed lower ecotoxic damage due to ZnCO
3
-like precipitation, indicating the effect of carbonates on Zn compounds during vegetable up-taking (exposure). Other environmental suggestions of the (Fe, Zn)S weathering and ecotoxic effects under calcareous soil conditions are discussed.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><pmid>38367090</pmid><doi>10.1007/s10653-024-01857-z</doi><tpages>1</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Environmental geochemistry and health, 2024-03, Vol.46 (3), p.87-87, Article 87 |
| issn | 0269-4042 1573-2983 |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Alkalinity Allium cepa Analytical methods Atomic force microscopy bulbs Calcareous soils Carbonates Carbonation Chemical speciation Damage dielectric spectroscopy Diffraction patterns Earth and Environmental Science Electrochemical impedance spectroscopy Electrochemistry Electron microscopy Environment Environmental Chemistry Environmental Health Ferric oxide Geochemistry Haematite Hematite Iron Iron carbonate Leachates Microscopy Original Paper Oxidation Public Health Raman spectroscopy redox potential Scanning electron microscopy Siderite smithsonite Soil Soil conditions Soil Science & Conservation Speciation species Spectroscopy Spectrum analysis Sphalerite sulfides Sulfur Sulphides Sulphur Terrestrial Pollution vegetables voltammetry Weathering X-ray diffraction Zinc Zinc ores Zinc sulfate Zincblende |
| title | Ecotoxic effect in Allium cepa due to sphalerite weathering arising in calcareous conditions |
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