Functionalization of the Octahydro-Binaphthol Skeleton: A Universal Strategy for Directly Constructing D–A Type Axially Chiral Biphenyl Luminescent Molecules

Functionalization of the Octahydro-Binaphthol Skeleton: A Universal Strategy for Directly Constructing D–A Type Axially Chiral Biphenyl Luminescent Molecules

D–A type axially chiral biphenyl luminescent molecules are directly constructed through ingenious functionalization of the octahydro-binaphthol skeleton without optical resolution. The circularly polarized organic light-emitting diodes based on them display remarkable circularly polarized electrolum...

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Veröffentlicht in:Journal of organic chemistry 2024-03, Vol.89 (5), p.3605-3611
Hauptverfasser: Jiang, Aiwei, Cui, Huihui, Zhang, Li, Cao, Chenhui, Dai, Hong, Lu, Chaowu, Ge, Cunwang, Lu, Hongbin, Wu, Zheng-Guang
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container_end_page 3611
container_issue 5
container_start_page 3605
container_title Journal of organic chemistry
container_volume 89
creator Jiang, Aiwei
Cui, Huihui
Zhang, Li
Cao, Chenhui
Dai, Hong
Lu, Chaowu
Ge, Cunwang
Lu, Hongbin
Wu, Zheng-Guang
description D–A type axially chiral biphenyl luminescent molecules are directly constructed through ingenious functionalization of the octahydro-binaphthol skeleton without optical resolution. The circularly polarized organic light-emitting diodes based on them display remarkable circularly polarized electroluminescence emission, a high luminance of >10 000 cd m–2, a maximum external quantum efficiency of 6.6%, and an extremely low-efficiency roll-off. This work provides a universal strategy for developing efficient and diverse axially chiral biphenyl emitters.
doi_str_mv 10.1021/acs.joc.3c02600
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title Functionalization of the Octahydro-Binaphthol Skeleton: A Universal Strategy for Directly Constructing D–A Type Axially Chiral Biphenyl Luminescent Molecules
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