Target-regulated photoactivities of CdS/Ni-MOF heterojunction with [Ru(bpy)2dppz]2+ intercalator: a bisphenol A photoelectrochemical aptasensor

Bisphenol A (BPA), an important endocrine disrupting compound, has infiltrated human daily lives through electronic devices, food containers, and children’s toys. Developing of novel BPA assay methods with high sensitivity holds tremendous importance in valuing the pollution state. Here, we construc...

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Veröffentlicht in:Mikrochimica acta (1966) 2024-03, Vol.191 (3), p.139-139, Article 139
Hauptverfasser: Tanjung, Aisyah Protonia, Yin, Ke, Zhao, Lei, Wu, Jiang-Zhou, Wang, Ai-Jun, Mei, Li-Ping, Song, Pei, Feng, Jiu-Ju
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container_end_page 139
container_issue 3
container_start_page 139
container_title Mikrochimica acta (1966)
container_volume 191
creator Tanjung, Aisyah Protonia
Yin, Ke
Zhao, Lei
Wu, Jiang-Zhou
Wang, Ai-Jun
Mei, Li-Ping
Song, Pei
Feng, Jiu-Ju
description Bisphenol A (BPA), an important endocrine disrupting compound, has infiltrated human daily lives through electronic devices, food containers, and children’s toys. Developing of novel BPA assay methods with high sensitivity holds tremendous importance in valuing the pollution state. Here, we constructed an ultrasensitive photoelectrochemical (PEC) aptasensor for BPA determination by regulating photoactivities of CdS/Ni-based metal–organic framework (CdS/Ni-MOF) with [Ru(bpy) 2 dppz] 2+ sensitizer. CdS/Ni-MOF spheres exhibited excellent photocatalytic performance, serving as a potential sensing platform for the construction of target recognition process. [Ru(bpy) 2 dppz] 2+ were embedded into DNA double-stranded structure, functioning as sensitizer for modulating the signal response of the developed PEC aptasensor. The proposed PEC sensor exhibited outstanding analytical performances, including a wide linear range (0.1 to 1000.0 nM), low detection limit (0.026 nM, at 3σ/m), excellent selectivity, and high stability. This work provides a perspective for the design of ideal photosensitive materials and signal amplification strategies and extends their application in environment analysis. Graphical Abstract
doi_str_mv 10.1007/s00604-024-06230-6
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subjects Analytical Chemistry
Benzhydryl Compounds
Biosensing Techniques - methods
Bisphenol A
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Child
DNA
Heterojunctions
Humans
Intercalating Agents
Metal-Organic Frameworks
Microengineering
Nanochemistry
Nanotechnology
Original Paper
Phenols
Photosensitivity
Target recognition
Toys
title Target-regulated photoactivities of CdS/Ni-MOF heterojunction with [Ru(bpy)2dppz]2+ intercalator: a bisphenol A photoelectrochemical aptasensor
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