Formation of diamond-like BN phases under shock compression of graphite-like BN with different degree of structural ordering

The formation of diamond-like modifications of BN under high-temperature shock compression ( P = 33 GPa and T up to 3500 K) has been studied. The powders of graphite-like BN with different degree of three-dimensional ordering of structure ( D 3) were used as starting materials. To increase shock tem...

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Veröffentlicht in:Diamond and related materials 2007-02, Vol.16 (2), p.267-276
Hauptverfasser: Britun, V.F., Kurdyumov, A.V., Borimchuk, N.I., Yarosh, V.V., Danilenko, A.I.
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container_end_page 276
container_issue 2
container_start_page 267
container_title Diamond and related materials
container_volume 16
creator Britun, V.F.
Kurdyumov, A.V.
Borimchuk, N.I.
Yarosh, V.V.
Danilenko, A.I.
description The formation of diamond-like modifications of BN under high-temperature shock compression ( P = 33 GPa and T up to 3500 K) has been studied. The powders of graphite-like BN with different degree of three-dimensional ordering of structure ( D 3) were used as starting materials. To increase shock temperature and preserve dense phase formed, boron nitride powder mixed with alkali halide salt was compressed in cylindrical ampoule. The recovered samples were studied by X-ray diffraction and electron microscopy. It was revealed that the phase composition of shock compression products depends on the degree of three-dimensional ordering of initial graphite-like structure. Turbostratic BN with disordered structure ( D 3 = 0) transformed mainly into cubic cBN by diffusion mechanism, whereas highly ordered graphite-like BN ( D 3 = 0.95) transformed only into wurtzite wBN by martensitic mechanism. Both cubic and wurtzite dense modifications are formed from partly ordered initial structures (for which D 3 was 0.45 ÷ 0.7). The both diamond-like phases have nanocrystalline structure.
doi_str_mv 10.1016/j.diamond.2006.06.017
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The powders of graphite-like BN with different degree of three-dimensional ordering of structure ( D 3) were used as starting materials. To increase shock temperature and preserve dense phase formed, boron nitride powder mixed with alkali halide salt was compressed in cylindrical ampoule. The recovered samples were studied by X-ray diffraction and electron microscopy. It was revealed that the phase composition of shock compression products depends on the degree of three-dimensional ordering of initial graphite-like structure. Turbostratic BN with disordered structure ( D 3 = 0) transformed mainly into cubic cBN by diffusion mechanism, whereas highly ordered graphite-like BN ( D 3 = 0.95) transformed only into wurtzite wBN by martensitic mechanism. Both cubic and wurtzite dense modifications are formed from partly ordered initial structures (for which D 3 was 0.45 ÷ 0.7). 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The powders of graphite-like BN with different degree of three-dimensional ordering of structure ( D 3) were used as starting materials. To increase shock temperature and preserve dense phase formed, boron nitride powder mixed with alkali halide salt was compressed in cylindrical ampoule. The recovered samples were studied by X-ray diffraction and electron microscopy. It was revealed that the phase composition of shock compression products depends on the degree of three-dimensional ordering of initial graphite-like structure. Turbostratic BN with disordered structure ( D 3 = 0) transformed mainly into cubic cBN by diffusion mechanism, whereas highly ordered graphite-like BN ( D 3 = 0.95) transformed only into wurtzite wBN by martensitic mechanism. Both cubic and wurtzite dense modifications are formed from partly ordered initial structures (for which D 3 was 0.45 ÷ 0.7). 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subjects Boron nitride
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Fullerenes and related materials
diamonds, graphite
High pressure
High temperature
Materials science
Nanocrystalline
Physics
Specific materials
title Formation of diamond-like BN phases under shock compression of graphite-like BN with different degree of structural ordering
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