Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles

Iron complexes bearing new silyl-NHC bidentate ligands were synthesised by treating Fe 3 (CO) 12 with a mixture of N -(hydrosilyl)methyl imidazolium salts and a base. These complexes showed high performance in the catalytic double hydroboration of nitrile with pinacolborane (HBpin) to produce N , N...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2024-02, Vol.53 (9), p.441-447
Hauptverfasser:	Komuro, Takashi, Hayasaka, Kohei, Takahashi, Kasumi, Ishiwata, Nozomu, Yamauchi, Kota, Tobita, Hiromi, Hashimoto, Hisako
Format:	Artikel
Sprache:	eng
Schlagworte:	Hydroboration Iron Ligands Nitriles NMR Nuclear magnetic resonance Ruthenium compounds Ultraviolet radiation
Online-Zugang:	Volltext
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