A bowl-shaped phosphangulene-protected cubic Cu58 nanocluster

A bowl-shaped phosphangulene-protected cubic Cu58 nanocluster

A bowl-shaped phosphangulene-protected cubic Cu58 nanocluster has been synthesized. The structure was determined by X-ray crystallography and further analyzed by multiple techniques. The phosphangulenes not only enable ligand substitutions with triphenylphosphines in a cluster-to-cluster transformat...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-02, Vol.60 (17), p.2389-2392
Hauptverfasser: Zhang, Qian, Zheng, Hao, Zhou, Jie, Jia-Ji, Yang, Kai-Yue, Xu, Lian-Yun, Shen, Zong-Jie Guan, Yang, Yang
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Crystallography
Nanoclusters
Photoelectric effect
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Zusammenfassung:A bowl-shaped phosphangulene-protected cubic Cu58 nanocluster has been synthesized. The structure was determined by X-ray crystallography and further analyzed by multiple techniques. The phosphangulenes not only enable ligand substitutions with triphenylphosphines in a cluster-to-cluster transformation way, but also facilitate inter-cluster interactions with fullerenes. These interactions further influence the entirety's photocurrent response and ability to liberate hydrogen when stimulated by light.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc05791g