Electron-triggered processes in halogenated carboxylates: dissociation pathways in CF3COCl and its clusters

Trifluoroacetyl chloride, CF3COCl, is produced in the Earth's atmosphere by photooxidative degradation of hydrochlorofluorocarbons, and represents a potential source of highly reactive halogen radicals. Despite considerable insight into photochemistry of CF3COCl, its reactivity towards electron...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2024-02, Vol.26 (6), p.5640-5648
Hauptverfasser:	Kocábková, Barbora, Ďurana, Jozef, Rakovský, Jozef, Pysanenko, Andrij, Fedor, Juraj, Ončák, Milan, Fárník, Michal
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylates Clusters Covalent bonds Electron attachment Electron energy Hydrochlorofluorocarbons Ionization Molecular beams Photochemistry Quantum chemistry Spectra
Online-Zugang:	Volltext
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