Description of exciton transport in a TiO2/MEH-PPV heterojunction photovoltaic material
A model for exciton transport in conjugated polymers has been developed taking into account inhomogeneous broadening of exciton energy level. Time-resolved photoluminescence data were used to determine the parameters of the model, such as exciton lifetime, effective number of exciton energy levels w...
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Veröffentlicht in: | Solar energy materials and solar cells 2005-05, Vol.87 (1-4), p.715-724 |
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container_title | Solar energy materials and solar cells |
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creator | KAWATA, K BURLAKOV, V. M CAREY, M. J ASSENDER, H. E BRIGGS, G. A. D RUSECKAS, A SAMUEL, I. D. W |
description | A model for exciton transport in conjugated polymers has been developed taking into account inhomogeneous broadening of exciton energy level. Time-resolved photoluminescence data were used to determine the parameters of the model, such as exciton lifetime, effective number of exciton energy levels within inhomogeneously broadened density of states, hopping distance and hopping rate constants for excitons. Using the developed model a non-monoexponential decay of photoluminescence of the conjugated polymer deposited on TiO2 substrate was described, and the spectrum of internal quantum efficiency of the heterojunction photovoltaic device based on the conjugated polymer with a nanocrystalline TiO2 layer was predicted. |
doi_str_mv | 10.1016/j.solmat.2004.07.046 |
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Using the developed model a non-monoexponential decay of photoluminescence of the conjugated polymer deposited on TiO2 substrate was described, and the spectrum of internal quantum efficiency of the heterojunction photovoltaic device based on the conjugated polymer with a nanocrystalline TiO2 layer was predicted.</description><identifier>ISSN: 0927-0248</identifier><identifier>EISSN: 1879-3398</identifier><identifier>DOI: 10.1016/j.solmat.2004.07.046</identifier><language>eng</language><publisher>Amsterdam: Elsevier</publisher><subject>Applied sciences ; Energy ; Equipments, installations and applications ; Exact sciences and technology ; Natural energy ; Photovoltaic conversion ; Solar cells. 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Using the developed model a non-monoexponential decay of photoluminescence of the conjugated polymer deposited on TiO2 substrate was described, and the spectrum of internal quantum efficiency of the heterojunction photovoltaic device based on the conjugated polymer with a nanocrystalline TiO2 layer was predicted.</description><subject>Applied sciences</subject><subject>Energy</subject><subject>Equipments, installations and applications</subject><subject>Exact sciences and technology</subject><subject>Natural energy</subject><subject>Photovoltaic conversion</subject><subject>Solar cells. 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subjects | Applied sciences Energy Equipments, installations and applications Exact sciences and technology Natural energy Photovoltaic conversion Solar cells. Photoelectrochemical cells Solar energy |
title | Description of exciton transport in a TiO2/MEH-PPV heterojunction photovoltaic material |
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