Post-annealing of Al-doped ZnO films in hydrogen atmosphere

Electrical properties of ZnO:Al films deposited on glass substrates by RF magnetron co-sputtering method have been modified by post-deposition annealing treatment in hydrogen atmosphere for potential transparent conductive oxide (TCO) applications. Annealing treatments were carried out at 573 K for...

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Veröffentlicht in:Journal of crystal growth 2005-08, Vol.281 (2), p.475-480
Hauptverfasser: Oh, Byeong-Yun, Jeong, Min-Chang, Kim, Doo-Soo, Lee, Woong, Myoung, Jae-Min
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container_issue 2
container_start_page 475
container_title Journal of crystal growth
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creator Oh, Byeong-Yun
Jeong, Min-Chang
Kim, Doo-Soo
Lee, Woong
Myoung, Jae-Min
description Electrical properties of ZnO:Al films deposited on glass substrates by RF magnetron co-sputtering method have been modified by post-deposition annealing treatment in hydrogen atmosphere for potential transparent conductive oxide (TCO) applications. Annealing treatments were carried out at 573 K for compatibility with typical display device fabrication processes and annealing time was varied between 10 and 120 min. Whereas there were no significant changes in crystallinity of the films, resistivity decreased from 4.80×10 −3 to 8.30×10 −4 Ω cm and carrier concentration increased from 2.11×10 20 to 8.86×10 20 cm −3 when annealing time was 60 min. Improved electrical properties are ascribed to desorption of the negatively charged oxygen species from the grain boundary surfaces by the hydrogen annealing treatment. The optical properties of the films, which change in accordance with the Burstein–Moss effect, are consistent with the observed changes in electrical properties.
doi_str_mv 10.1016/j.jcrysgro.2005.04.045
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subjects A1. Hydrogen passivation
B1. Al-doped ZnO (ZnO:Al)
B1. Transparent conductive oxide (TCO)
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Methods of crystal growth
physics of crystal growth
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Physics
title Post-annealing of Al-doped ZnO films in hydrogen atmosphere
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