Route to Functionalized Tetrahydrobenzo[d]azepines via Re2O7‑Mediated Intramolecular Friedel–Crafts Reaction

We describe a Re2O7-mediated intramolecular dehydrative Friedel–Crafts reaction for the efficient synthesis of various benzo-fused heterocycles such as benzazepines and benzazocines. This process is characterized by a broad substrate scope, mild reaction conditions, high efficiency, and high atom ec...

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Veröffentlicht in:	Journal of organic chemistry 2024-02, Vol.89 (3), p.2001-2008
Hauptverfasser:	Zheng, Yuzhu, Huang, Qing, Fang, Xiong, Xie, Youwei
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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