A Rational Way to Control the Triplet State Wave Function Confinement of Organic Chromophores: Effect of the Connection Sites and Spin Density Distribution-Guided Molecular Structure Design Principles in Bodipy Dimers

To study the intersystem crossing (ISC) and the spatial confinement of the triplet excited states of organic chromophores, we prepared a series of Bodipy dimers. We found that the connection position of the two units has a significant effect on the absorption and fluorescence. Singlet oxygen quantum...

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Veröffentlicht in:The journal of physical chemistry letters 2024-02, Vol.15 (4), p.959-968
Hauptverfasser: Wu, Yanran, Cao, Huaiman, Bakirov, Marcel M., Sukhanov, Andrey A., Li, Jiayu, Liao, Sheng, Xiao, Xiao, Zhao, Jianzhang, Li, Ming-De, Kandrashkin, Yuri E.
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