Physico-chemical and X-ray optical characterizations of a Mo/Si multilayer interferential mirror upon annealing

We investigate on a Mo/Si multilayer interferential mirror (MIM) as a function of annealing at temperatures up to 600 °C. The physicochemical state of the silicon atoms within the MIM is characterized by X-ray emission spectroscopy (XES). A thin silicide layer is detected at the interfaces of the as...

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Veröffentlicht in:Surface science 2005-09, Vol.589 (1), p.164-172
Hauptverfasser: Jonnard, P., Jarrige, I., Benbalagh, R., Maury, H., André, J.-M., Dankházi, Z., Rolland, G.
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container_end_page 172
container_issue 1
container_start_page 164
container_title Surface science
container_volume 589
creator Jonnard, P.
Jarrige, I.
Benbalagh, R.
Maury, H.
André, J.-M.
Dankházi, Z.
Rolland, G.
description We investigate on a Mo/Si multilayer interferential mirror (MIM) as a function of annealing at temperatures up to 600 °C. The physicochemical state of the silicon atoms within the MIM is characterized by X-ray emission spectroscopy (XES). A thin silicide layer is detected at the interfaces of the as-prepared system, whose thickness increases upon annealing. Measurements of the reflecting power at 1.33 nm show that both the reflectivity and the period markedly decrease as the annealing temperature increases, thus stressing on the interplay between the interface physico-chemical state and the optical properties. Our results shed light on the highest temperature regime, 600 °C, where the MIM loses its periodic structure as the majority of the silicon atoms are involved in the MoSi 2 compound. The diffusion coefficient is estimated from the evolution of the reflected intensity and the period. An activation energy of the diffusion process of 0.52 eV is deduced.
doi_str_mv 10.1016/j.susc.2005.05.058
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source ScienceDirect Journals (5 years ago - present)
subjects Annealing
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Diffusion
Electronic structure
Exact sciences and technology
Interface
Molybdenum
Physics
Silicide
Silicon
X-ray emission spectroscopy
X-ray reflectivity
title Physico-chemical and X-ray optical characterizations of a Mo/Si multilayer interferential mirror upon annealing
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