A General Platform for Visible Light Sulfonylation Reactions Enabled by Catalytic Triarylamine EDA Complexes
Catalytic electron donor–acceptor (EDA) complexes have recently emerged as a powerful and sustainable alternative to iridium- and ruthenium-based photoredox synthetic methods. Yet, these complexes remain underexplored and reliant on the use of meticulously designed acceptors that require previous in...
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| Veröffentlicht in: | Journal of the American Chemical Society 2024-01, Vol.146 (4), p.2583-2592 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 146 |
| creator | Lasso, Juan D. Castillo-Pazos, Durbis J. Salgado, Jan Michael Ruchlin, Cory Lefebvre, Loric Farajat, Daliah Perepichka, Dmytro F. Li, Chao-Jun |
| description | Catalytic electron donor–acceptor (EDA) complexes have recently emerged as a powerful and sustainable alternative to iridium- and ruthenium-based photoredox synthetic methods. Yet, these complexes remain underexplored and reliant on the use of meticulously designed acceptors that require previous installation. Herein, we report a novel EDA complex employing tris(4-methoxyphenyl) amine as a catalytic donor for the sulfonylation of alkenes using inexpensive and readily available sulfonyl chlorides. Applying this operationally simple, visible-light-mediated general platform, we report both the redox-neutral and net-reductive functionalization of more than 60 substrates, encompassing vinylic or allylic sulfonylation, hydrosulfonylation, and sulfamoylation of activated and unactivated alkenes and alkynes. |
| doi_str_mv | 10.1021/jacs.3c11225 |
| format | Article |
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| title | A General Platform for Visible Light Sulfonylation Reactions Enabled by Catalytic Triarylamine EDA Complexes |
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