Bioinspired Total Synthesis of (+)-Kopsiyunnanine B

The first enantioselective total synthesis of kopsiyunnanine B, which has a unique folded and complex pentacyclic structure containing six contiguous chiral centers, has been achieved along our originally proposed biosynthetic pathway. The key reaction of this synthesis includes a bioinspired cascad...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 2024/01/17, Vol.72(1), pp.68-74
Hauptverfasser:	Imaoka, Sho, Nakashima, Yuta, Kitajima, Mariko, Ishikawa, Hayato
Format:	Artikel
Sprache:	eng
Schlagworte:	bioinspired reaction cascade reaction Chemical synthesis Enantiomers Kopsia alkaloid Oxidation oxindole alkaloid Ring structures Stereoselectivity total synthesis
Online-Zugang:	Volltext
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