Polyacetylene‐Based Asymmetric Bicyclic Polymer by Blocking‐Cyclization Technique
A rare asymmetric bicyclic polymer containing different length of conjugated polyacetylene segments is synthesized by metathesis cyclopolymerization‐mediated blocking‐cyclization technique. The size of each single ring differs from each other, and the unique cyclic polymer topology is controlled by...
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| Veröffentlicht in: | Macromolecular rapid communications. 2024-03, Vol.45 (6), p.e2300628-n/a |
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| creator | Ma, Cuihong Wang, Hao Sun, Ruyi Liao, Xiaojuan Han, Huijing Xie, Meiran |
| description | A rare asymmetric bicyclic polymer containing different length of conjugated polyacetylene segments is synthesized by metathesis cyclopolymerization‐mediated blocking‐cyclization technique. The size of each single ring differs from each other, and the unique cyclic polymer topology is controlled by adjusting the feed ratio of monofunctional monomer to catalyst. The topological difference between linear and bicyclic polymers is confirmed by several techniques, and the visualized morphology of asymmetric bicyclic polymer is directly observed without tedious post‐modification process. The photoelectric and thermal properties of polymers are investigated. This work expands the pathway for the derivation of cyclic polymers, and such unique topological structure enriches the diversity of cyclic polymer classes.
Polyacetylene‐based bicyclic polymer with asymmetric cyclic topology is synthesized by metathesis cyclopolymerization‐mediated blocking‐cyclization technique, and the unique molecular topology is directly observed without tedious post‐modification process. |
| doi_str_mv | 10.1002/marc.202300628 |
| format | Article |
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Polyacetylene‐based bicyclic polymer with asymmetric cyclic topology is synthesized by metathesis cyclopolymerization‐mediated blocking‐cyclization technique, and the unique molecular topology is directly observed without tedious post‐modification process.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.202300628</identifier><identifier>PMID: 38227809</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>asymmetric bicyclic polymer ; Asymmetry ; blocking‐cyclization technique ; Catalysts ; Mathematical morphology ; Metathesis ; metathesis cyclopolymerization ; photoelectric properties ; Photoelectricity ; Polyacetylene ; Polymers ; Rings (mathematics) ; Thermal properties ; Thermodynamic properties ; Topology</subject><ispartof>Macromolecular rapid communications., 2024-03, Vol.45 (6), p.e2300628-n/a</ispartof><rights>2024 Wiley‐VCH GmbH</rights><rights>2024 Wiley‐VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c3288-34e81126462ad428cc18c9f724d6a27a40c68b889881fe6aea40f3a68196a9293</cites><orcidid>0000-0002-7411-3927</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.202300628$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.202300628$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38227809$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ma, Cuihong</creatorcontrib><creatorcontrib>Wang, Hao</creatorcontrib><creatorcontrib>Sun, Ruyi</creatorcontrib><creatorcontrib>Liao, Xiaojuan</creatorcontrib><creatorcontrib>Han, Huijing</creatorcontrib><creatorcontrib>Xie, Meiran</creatorcontrib><title>Polyacetylene‐Based Asymmetric Bicyclic Polymer by Blocking‐Cyclization Technique</title><title>Macromolecular rapid communications.</title><addtitle>Macromol Rapid Commun</addtitle><description>A rare asymmetric bicyclic polymer containing different length of conjugated polyacetylene segments is synthesized by metathesis cyclopolymerization‐mediated blocking‐cyclization technique. The size of each single ring differs from each other, and the unique cyclic polymer topology is controlled by adjusting the feed ratio of monofunctional monomer to catalyst. The topological difference between linear and bicyclic polymers is confirmed by several techniques, and the visualized morphology of asymmetric bicyclic polymer is directly observed without tedious post‐modification process. The photoelectric and thermal properties of polymers are investigated. This work expands the pathway for the derivation of cyclic polymers, and such unique topological structure enriches the diversity of cyclic polymer classes.
Polyacetylene‐based bicyclic polymer with asymmetric cyclic topology is synthesized by metathesis cyclopolymerization‐mediated blocking‐cyclization technique, and the unique molecular topology is directly observed without tedious post‐modification process.</description><subject>asymmetric bicyclic polymer</subject><subject>Asymmetry</subject><subject>blocking‐cyclization technique</subject><subject>Catalysts</subject><subject>Mathematical morphology</subject><subject>Metathesis</subject><subject>metathesis cyclopolymerization</subject><subject>photoelectric properties</subject><subject>Photoelectricity</subject><subject>Polyacetylene</subject><subject>Polymers</subject><subject>Rings (mathematics)</subject><subject>Thermal properties</subject><subject>Thermodynamic properties</subject><subject>Topology</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EouWxZYkisWGTYo9Tx162ES-pCITadeQ6E0jJo8SNUFjxCXwjX4KjliKxYeWR58yd0SHkhNEBoxQuCl2bAVDglAqQO6TPhsB8riDcdTUF8BnnokcOrF1QSmVAYZ_0uAQIJVV9Mnuo8lYbXLU5lvj18TnWFhNvZNuiwFWdGW-cmdbkrujIAmtv3nrjvDIvWfnk-KhrvutVVpXeFM1zmb02eET2Up1bPN68h2R2dTmNbvzJ_fVtNJr4hoOUPg9QMgYiEKCTAKQxTBqVhhAkQkOoA2qEnEuppGQpCo3uJ-VaSKaEVqD4ITlf5y7ryq21q7jIrME81yVWjY1BsaEbDkNw6NkfdFE1demuc1QIQomQckcN1pSpK2trTONlnTnHbcxo3AmPO-HxVrgbON3ENvMCky3-Y9gBag28ZTm2_8TFd6PH6Df8G5v2jdA</recordid><startdate>202403</startdate><enddate>202403</enddate><creator>Ma, Cuihong</creator><creator>Wang, Hao</creator><creator>Sun, Ruyi</creator><creator>Liao, Xiaojuan</creator><creator>Han, Huijing</creator><creator>Xie, Meiran</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>JQ2</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7411-3927</orcidid></search><sort><creationdate>202403</creationdate><title>Polyacetylene‐Based Asymmetric Bicyclic Polymer by Blocking‐Cyclization Technique</title><author>Ma, Cuihong ; Wang, Hao ; Sun, Ruyi ; Liao, Xiaojuan ; Han, Huijing ; Xie, Meiran</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3288-34e81126462ad428cc18c9f724d6a27a40c68b889881fe6aea40f3a68196a9293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>asymmetric bicyclic polymer</topic><topic>Asymmetry</topic><topic>blocking‐cyclization technique</topic><topic>Catalysts</topic><topic>Mathematical morphology</topic><topic>Metathesis</topic><topic>metathesis cyclopolymerization</topic><topic>photoelectric properties</topic><topic>Photoelectricity</topic><topic>Polyacetylene</topic><topic>Polymers</topic><topic>Rings (mathematics)</topic><topic>Thermal properties</topic><topic>Thermodynamic properties</topic><topic>Topology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Cuihong</creatorcontrib><creatorcontrib>Wang, Hao</creatorcontrib><creatorcontrib>Sun, Ruyi</creatorcontrib><creatorcontrib>Liao, Xiaojuan</creatorcontrib><creatorcontrib>Han, Huijing</creatorcontrib><creatorcontrib>Xie, Meiran</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Cuihong</au><au>Wang, Hao</au><au>Sun, Ruyi</au><au>Liao, Xiaojuan</au><au>Han, Huijing</au><au>Xie, Meiran</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polyacetylene‐Based Asymmetric Bicyclic Polymer by Blocking‐Cyclization Technique</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol Rapid Commun</addtitle><date>2024-03</date><risdate>2024</risdate><volume>45</volume><issue>6</issue><spage>e2300628</spage><epage>n/a</epage><pages>e2300628-n/a</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>A rare asymmetric bicyclic polymer containing different length of conjugated polyacetylene segments is synthesized by metathesis cyclopolymerization‐mediated blocking‐cyclization technique. The size of each single ring differs from each other, and the unique cyclic polymer topology is controlled by adjusting the feed ratio of monofunctional monomer to catalyst. The topological difference between linear and bicyclic polymers is confirmed by several techniques, and the visualized morphology of asymmetric bicyclic polymer is directly observed without tedious post‐modification process. The photoelectric and thermal properties of polymers are investigated. This work expands the pathway for the derivation of cyclic polymers, and such unique topological structure enriches the diversity of cyclic polymer classes.
Polyacetylene‐based bicyclic polymer with asymmetric cyclic topology is synthesized by metathesis cyclopolymerization‐mediated blocking‐cyclization technique, and the unique molecular topology is directly observed without tedious post‐modification process.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>38227809</pmid><doi>10.1002/marc.202300628</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-7411-3927</orcidid></addata></record> |
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| subjects | asymmetric bicyclic polymer Asymmetry blocking‐cyclization technique Catalysts Mathematical morphology Metathesis metathesis cyclopolymerization photoelectric properties Photoelectricity Polyacetylene Polymers Rings (mathematics) Thermal properties Thermodynamic properties Topology |
| title | Polyacetylene‐Based Asymmetric Bicyclic Polymer by Blocking‐Cyclization Technique |
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