Chemoselectivity Inversion of Responsive Metal–Organic Frameworks by Particle Size Tuning in the Micrometer Regime

Gated adsorption is one of the unique physical properties of flexible metal–organic frameworks with high application potential in selective adsorption and sensing of molecules. Despite recent studies that have provided some guidelines in understanding and designing structural flexibility for control...

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Veröffentlicht in:	Small (Weinheim an der Bergstrasse, Germany) Germany), 2024-06, Vol.20 (24), p.e2307285-n/a
Hauptverfasser:	Abylgazina, Leila, Senkovska, Irena, Engemann, Richard, Bönisch, Nadine, Gorelik, Tatiana E., Bachetzky, Christopher, Kaiser, Ute, Brunner, Eike, Kaskel, Stefan
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Alcohols chemoselectivity crystal size Dichloromethane Downsizing Metal-organic frameworks Microcrystals morphology Particle size Phase transitions Physical properties Selective adsorption Selectivity switchability
Online-Zugang:	Volltext
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