Laser heated pedestal growth and optical characterization of CaTa2O6 single crystal fiber
Transparent, colorless 30 mm long, (705 - 11)mum diameter CaTa2O6 single crystal fibers with a cubic crystalline structure (Pm3) were grown by the Laser Heated Pedestal Growth technique. The lattice parameter was a = (7.757 plus/minus 0.002)A obtained from the Rietveld refinement. The fiber growth d...
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Veröffentlicht in: | Journal of crystal growth 2004-06, Vol.266 (4), p.475-480 |
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description | Transparent, colorless 30 mm long, (705 - 11)mum diameter CaTa2O6 single crystal fibers with a cubic crystalline structure (Pm3) were grown by the Laser Heated Pedestal Growth technique. The lattice parameter was a = (7.757 plus/minus 0.002)A obtained from the Rietveld refinement. The fiber growth direction was determined as [1 0 1] by X-ray diffraction. The growth temperature was (2040 plus/minus 100)DGC and the axial temperature gradient measured at the crystallization interface was (7.5 plus/minus 1.0) x 103 DGC/cm. The fiber/pedestal-pulling ratio was equal to 1.20. Undoped samples were characterized by optical microscopy, X-ray diffraction patterns, infrared transmission and Raman scattering. The structural and spectroscopic results indicate that this crystal may have potential as a host for active ions such as neodymium and erbium which have interesting emissions in the near-infrared region. |
doi_str_mv | 10.1016/j.jcrysgro.2004.03.001 |
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R ; DE CAMARGO, A. S. S ; NUNES, L. A. O ; HERNANDES, A. C</creator><creatorcontrib>FERRARI, C. R ; DE CAMARGO, A. S. S ; NUNES, L. A. O ; HERNANDES, A. C</creatorcontrib><description>Transparent, colorless 30 mm long, (705 - 11)mum diameter CaTa2O6 single crystal fibers with a cubic crystalline structure (Pm3) were grown by the Laser Heated Pedestal Growth technique. The lattice parameter was a = (7.757 plus/minus 0.002)A obtained from the Rietveld refinement. The fiber growth direction was determined as [1 0 1] by X-ray diffraction. The growth temperature was (2040 plus/minus 100)DGC and the axial temperature gradient measured at the crystallization interface was (7.5 plus/minus 1.0) x 103 DGC/cm. The fiber/pedestal-pulling ratio was equal to 1.20. Undoped samples were characterized by optical microscopy, X-ray diffraction patterns, infrared transmission and Raman scattering. 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Undoped samples were characterized by optical microscopy, X-ray diffraction patterns, infrared transmission and Raman scattering. The structural and spectroscopic results indicate that this crystal may have potential as a host for active ions such as neodymium and erbium which have interesting emissions in the near-infrared region.</description><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Growth from melts; zone melting and refining</subject><subject>Materials science</subject><subject>Methods of crystal growth; physics of crystal growth</subject><subject>Physics</subject><issn>0022-0248</issn><issn>1873-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqNkM1OwzAQhC0EEqXwCsgXuCWs7Th2jqjiT6rUSzlwshzHaR2lSbBTofL0OGoRVy670mpmdvQhdEsgJUDyhyZtjD-Eje9TCpClwFIAcoZmRAqWcAB6jmZx0gRoJi_RVQgNREVOYIY-ljpYj7dWj7bCg61sGHWLY9jXuMW6q3A_jM7Ek9lqr81ovfvWo-s73Nd4odearnIcXLdpLZ5qTO7aldZfo4tat8HenPYcvT8_rRevyXL18rZ4XCaGCjEmREqe1brggmhJ85oxZk0JZSkysKIqeSlNJowtoGRQsYLzeKM0E7IiLM8om6P7Y-7g-899rK92Lhjbtrqz_T4oWpCMMfkPoZQAkk3C_Cg0vg_B21oN3u20PygCakKuGvWLXE3IFTAVgUbj3emDDhFZ7XVnXPhzc8k45YL9AKJxhEM</recordid><startdate>20040601</startdate><enddate>20040601</enddate><creator>FERRARI, C. 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C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Laser heated pedestal growth and optical characterization of CaTa2O6 single crystal fiber</atitle><jtitle>Journal of crystal growth</jtitle><date>2004-06-01</date><risdate>2004</risdate><volume>266</volume><issue>4</issue><spage>475</spage><epage>480</epage><pages>475-480</pages><issn>0022-0248</issn><eissn>1873-5002</eissn><coden>JCRGAE</coden><abstract>Transparent, colorless 30 mm long, (705 - 11)mum diameter CaTa2O6 single crystal fibers with a cubic crystalline structure (Pm3) were grown by the Laser Heated Pedestal Growth technique. The lattice parameter was a = (7.757 plus/minus 0.002)A obtained from the Rietveld refinement. The fiber growth direction was determined as [1 0 1] by X-ray diffraction. The growth temperature was (2040 plus/minus 100)DGC and the axial temperature gradient measured at the crystallization interface was (7.5 plus/minus 1.0) x 103 DGC/cm. The fiber/pedestal-pulling ratio was equal to 1.20. Undoped samples were characterized by optical microscopy, X-ray diffraction patterns, infrared transmission and Raman scattering. The structural and spectroscopic results indicate that this crystal may have potential as a host for active ions such as neodymium and erbium which have interesting emissions in the near-infrared region.</abstract><cop>Amsterdam</cop><pub>Elsevier</pub><doi>10.1016/j.jcrysgro.2004.03.001</doi><tpages>6</tpages></addata></record> |
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subjects | Cross-disciplinary physics: materials science rheology Exact sciences and technology Growth from melts zone melting and refining Materials science Methods of crystal growth physics of crystal growth Physics |
title | Laser heated pedestal growth and optical characterization of CaTa2O6 single crystal fiber |
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