Zharchikhite, AlF(OH)2: a novel structure type related to α‐PbO2
The crystal structure of zharchikhite, AlF(OH)2, from the Zharchikhinskoe deposit (Buryatia, Russia) is solved here using single‐crystal X‐ray diffraction. The mineral is monoclinic, space group P21/c, a = 5.1788 (4), b = 7.8386 (4), c = 5.1624 (4) Å, β = 116.276 (10)°, V = 187.91 (3) Å3 and Z = 4....
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Veröffentlicht in: | Acta crystallographica Section B, Structural science, crystal engineering and materials Structural science, crystal engineering and materials, 2024-02, Vol.80 (1), p.38-41 |
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container_title | Acta crystallographica Section B, Structural science, crystal engineering and materials |
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creator | Zubkova, Natalia V. Pekov, Igor V. Ksenofontov, Dmitry A. Pushcharovsky, Dmitry Yu |
description | The crystal structure of zharchikhite, AlF(OH)2, from the Zharchikhinskoe deposit (Buryatia, Russia) is solved here using single‐crystal X‐ray diffraction. The mineral is monoclinic, space group P21/c, a = 5.1788 (4), b = 7.8386 (4), c = 5.1624 (4) Å, β = 116.276 (10)°, V = 187.91 (3) Å3 and Z = 4. Zharchikhite demonstrates a novel structure type roughly related to the α‐PbO2 structure type and different from other compounds of the Al–F–OH system. The crystal structure of zharchikhite is based on the octahedral pseudoframework built from zigzag chains of edge‐sharing AlF2(OH)4 octahedra; adjacent chains are linked via F vertices and the pseudoframework contains wide channels.
The crystal structure of zharchikhite, AlF(OH)2, is solved here. Zharchikhite exhibits a novel structure type roughly related to α‐PbO2 structure type. |
doi_str_mv | 10.1107/S2052520623010491 |
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The crystal structure of zharchikhite, AlF(OH)2, is solved here. Zharchikhite exhibits a novel structure type roughly related to α‐PbO2 structure type.</description><identifier>ISSN: 2052-5206</identifier><identifier>ISSN: 2052-5192</identifier><identifier>EISSN: 2052-5206</identifier><identifier>DOI: 10.1107/S2052520623010491</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>aluminium hydroxyfluoride ; aluminofluoride ; Apexes ; Crystal structure ; Lead oxides ; Zharchikhinskoe deposit ; zharchikhite ; α‐PbO2 structure type</subject><ispartof>Acta crystallographica Section B, Structural science, crystal engineering and materials, 2024-02, Vol.80 (1), p.38-41</ispartof><rights>2024 Natalia V. Zubkova et al. published by IUCr Journals.</rights><rights>Copyright Blackwell Publishing Ltd. Feb 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS2052520623010491$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS2052520623010491$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Zubkova, Natalia V.</creatorcontrib><creatorcontrib>Pekov, Igor V.</creatorcontrib><creatorcontrib>Ksenofontov, Dmitry A.</creatorcontrib><creatorcontrib>Pushcharovsky, Dmitry Yu</creatorcontrib><title>Zharchikhite, AlF(OH)2: a novel structure type related to α‐PbO2</title><title>Acta crystallographica Section B, Structural science, crystal engineering and materials</title><description>The crystal structure of zharchikhite, AlF(OH)2, from the Zharchikhinskoe deposit (Buryatia, Russia) is solved here using single‐crystal X‐ray diffraction. The mineral is monoclinic, space group P21/c, a = 5.1788 (4), b = 7.8386 (4), c = 5.1624 (4) Å, β = 116.276 (10)°, V = 187.91 (3) Å3 and Z = 4. Zharchikhite demonstrates a novel structure type roughly related to the α‐PbO2 structure type and different from other compounds of the Al–F–OH system. The crystal structure of zharchikhite is based on the octahedral pseudoframework built from zigzag chains of edge‐sharing AlF2(OH)4 octahedra; adjacent chains are linked via F vertices and the pseudoframework contains wide channels.
The crystal structure of zharchikhite, AlF(OH)2, is solved here. Zharchikhite exhibits a novel structure type roughly related to α‐PbO2 structure type.</description><subject>aluminium hydroxyfluoride</subject><subject>aluminofluoride</subject><subject>Apexes</subject><subject>Crystal structure</subject><subject>Lead oxides</subject><subject>Zharchikhinskoe deposit</subject><subject>zharchikhite</subject><subject>α‐PbO2 structure type</subject><issn>2052-5206</issn><issn>2052-5192</issn><issn>2052-5206</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNplkEFKw0AYhQdRsNQewN2AmwpG5_-TmWbc1WqtWKigLnQTZiZTmjpt4iRRuvMIXsWLeAhPYkpdiK7-x-N7j59HyD6wYwDWO7lFxpEjExgyYJGELdJaW8Ha2_6ld0mnLOeMsSbGUUCLDB5nyptZ9jTLKntE-27YnYwO8ZQqusxfrKNl5WtT1d7SalVY6q1TlU1pldPPj6-39xs9wT2yM1WutJ2f2yb3w4u7wSgYTy6vBv1xUEAMIkjTVJupilOldcxkbHWkjZbCRgJBoo64inssVVJNkSsAg6i1tDETkQFIZdgm3U1v4fPn2pZVsshKY51TS5vXZYISwogzLqBBD_6g87z2y-a7hkKMox4H3lByQ71mzq6SwmcL5VcJsGQ9a_Jv1qT_cIbn1xxQhN9ye2tw</recordid><startdate>202402</startdate><enddate>202402</enddate><creator>Zubkova, Natalia V.</creator><creator>Pekov, Igor V.</creator><creator>Ksenofontov, Dmitry A.</creator><creator>Pushcharovsky, Dmitry Yu</creator><general>International Union of Crystallography</general><general>Blackwell Publishing Ltd</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope></search><sort><creationdate>202402</creationdate><title>Zharchikhite, AlF(OH)2: a novel structure type related to α‐PbO2</title><author>Zubkova, Natalia V. ; Pekov, Igor V. ; Ksenofontov, Dmitry A. ; Pushcharovsky, Dmitry Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1816-dddbcfa8dabb8098eb4bcb96e462192b45a870da9af25a11c22bb9e8064c11d93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>aluminium hydroxyfluoride</topic><topic>aluminofluoride</topic><topic>Apexes</topic><topic>Crystal structure</topic><topic>Lead oxides</topic><topic>Zharchikhinskoe deposit</topic><topic>zharchikhite</topic><topic>α‐PbO2 structure type</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zubkova, Natalia V.</creatorcontrib><creatorcontrib>Pekov, Igor V.</creatorcontrib><creatorcontrib>Ksenofontov, Dmitry A.</creatorcontrib><creatorcontrib>Pushcharovsky, Dmitry Yu</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica Section B, Structural science, crystal engineering and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zubkova, Natalia V.</au><au>Pekov, Igor V.</au><au>Ksenofontov, Dmitry A.</au><au>Pushcharovsky, Dmitry Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zharchikhite, AlF(OH)2: a novel structure type related to α‐PbO2</atitle><jtitle>Acta crystallographica Section B, Structural science, crystal engineering and materials</jtitle><date>2024-02</date><risdate>2024</risdate><volume>80</volume><issue>1</issue><spage>38</spage><epage>41</epage><pages>38-41</pages><issn>2052-5206</issn><issn>2052-5192</issn><eissn>2052-5206</eissn><abstract>The crystal structure of zharchikhite, AlF(OH)2, from the Zharchikhinskoe deposit (Buryatia, Russia) is solved here using single‐crystal X‐ray diffraction. The mineral is monoclinic, space group P21/c, a = 5.1788 (4), b = 7.8386 (4), c = 5.1624 (4) Å, β = 116.276 (10)°, V = 187.91 (3) Å3 and Z = 4. Zharchikhite demonstrates a novel structure type roughly related to the α‐PbO2 structure type and different from other compounds of the Al–F–OH system. The crystal structure of zharchikhite is based on the octahedral pseudoframework built from zigzag chains of edge‐sharing AlF2(OH)4 octahedra; adjacent chains are linked via F vertices and the pseudoframework contains wide channels.
The crystal structure of zharchikhite, AlF(OH)2, is solved here. Zharchikhite exhibits a novel structure type roughly related to α‐PbO2 structure type.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><doi>10.1107/S2052520623010491</doi><tpages>4</tpages></addata></record> |
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subjects | aluminium hydroxyfluoride aluminofluoride Apexes Crystal structure Lead oxides Zharchikhinskoe deposit zharchikhite α‐PbO2 structure type |
title | Zharchikhite, AlF(OH)2: a novel structure type related to α‐PbO2 |
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