Zharchikhite, AlF(OH)2: a novel structure type related to α‐PbO2

The crystal structure of zharchikhite, AlF(OH)2, from the Zharchikhinskoe deposit (Buryatia, Russia) is solved here using single‐crystal X‐ray diffraction. The mineral is monoclinic, space group P21/c, a = 5.1788 (4), b = 7.8386 (4), c = 5.1624 (4) Å, β = 116.276 (10)°, V = 187.91 (3) Å3 and Z = 4....

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Veröffentlicht in:Acta crystallographica Section B, Structural science, crystal engineering and materials Structural science, crystal engineering and materials, 2024-02, Vol.80 (1), p.38-41
Hauptverfasser: Zubkova, Natalia V., Pekov, Igor V., Ksenofontov, Dmitry A., Pushcharovsky, Dmitry Yu
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container_title Acta crystallographica Section B, Structural science, crystal engineering and materials
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creator Zubkova, Natalia V.
Pekov, Igor V.
Ksenofontov, Dmitry A.
Pushcharovsky, Dmitry Yu
description The crystal structure of zharchikhite, AlF(OH)2, from the Zharchikhinskoe deposit (Buryatia, Russia) is solved here using single‐crystal X‐ray diffraction. The mineral is monoclinic, space group P21/c, a = 5.1788 (4), b = 7.8386 (4), c = 5.1624 (4) Å, β = 116.276 (10)°, V = 187.91 (3) Å3 and Z = 4. Zharchikhite demonstrates a novel structure type roughly related to the α‐PbO2 structure type and different from other compounds of the Al–F–OH system. The crystal structure of zharchikhite is based on the octahedral pseudoframework built from zigzag chains of edge‐sharing AlF2(OH)4 octahedra; adjacent chains are linked via F vertices and the pseudoframework contains wide channels. The crystal structure of zharchikhite, AlF(OH)2, is solved here. Zharchikhite exhibits a novel structure type roughly related to α‐PbO2 structure type.
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Zharchikhite exhibits a novel structure type roughly related to α‐PbO2 structure type.</description><subject>aluminium hydroxyfluoride</subject><subject>aluminofluoride</subject><subject>Apexes</subject><subject>Crystal structure</subject><subject>Lead oxides</subject><subject>Zharchikhinskoe deposit</subject><subject>zharchikhite</subject><subject>α‐PbO2 structure type</subject><issn>2052-5206</issn><issn>2052-5192</issn><issn>2052-5206</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNplkEFKw0AYhQdRsNQewN2AmwpG5_-TmWbc1WqtWKigLnQTZiZTmjpt4iRRuvMIXsWLeAhPYkpdiK7-x-N7j59HyD6wYwDWO7lFxpEjExgyYJGELdJaW8Ha2_6ld0mnLOeMsSbGUUCLDB5nyptZ9jTLKntE-27YnYwO8ZQqusxfrKNl5WtT1d7SalVY6q1TlU1pldPPj6-39xs9wT2yM1WutJ2f2yb3w4u7wSgYTy6vBv1xUEAMIkjTVJupilOldcxkbHWkjZbCRgJBoo64inssVVJNkSsAg6i1tDETkQFIZdgm3U1v4fPn2pZVsshKY51TS5vXZYISwogzLqBBD_6g87z2y-a7hkKMox4H3lByQ71mzq6SwmcL5VcJsGQ9a_Jv1qT_cIbn1xxQhN9ye2tw</recordid><startdate>202402</startdate><enddate>202402</enddate><creator>Zubkova, Natalia V.</creator><creator>Pekov, Igor V.</creator><creator>Ksenofontov, Dmitry A.</creator><creator>Pushcharovsky, Dmitry Yu</creator><general>International Union of Crystallography</general><general>Blackwell Publishing Ltd</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope></search><sort><creationdate>202402</creationdate><title>Zharchikhite, AlF(OH)2: a novel structure type related to α‐PbO2</title><author>Zubkova, Natalia V. ; Pekov, Igor V. ; Ksenofontov, Dmitry A. ; Pushcharovsky, Dmitry Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1816-dddbcfa8dabb8098eb4bcb96e462192b45a870da9af25a11c22bb9e8064c11d93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>aluminium hydroxyfluoride</topic><topic>aluminofluoride</topic><topic>Apexes</topic><topic>Crystal structure</topic><topic>Lead oxides</topic><topic>Zharchikhinskoe deposit</topic><topic>zharchikhite</topic><topic>α‐PbO2 structure type</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zubkova, Natalia V.</creatorcontrib><creatorcontrib>Pekov, Igor V.</creatorcontrib><creatorcontrib>Ksenofontov, Dmitry A.</creatorcontrib><creatorcontrib>Pushcharovsky, Dmitry Yu</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica Section B, Structural science, crystal engineering and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zubkova, Natalia V.</au><au>Pekov, Igor V.</au><au>Ksenofontov, Dmitry A.</au><au>Pushcharovsky, Dmitry Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zharchikhite, AlF(OH)2: a novel structure type related to α‐PbO2</atitle><jtitle>Acta crystallographica Section B, Structural science, crystal engineering and materials</jtitle><date>2024-02</date><risdate>2024</risdate><volume>80</volume><issue>1</issue><spage>38</spage><epage>41</epage><pages>38-41</pages><issn>2052-5206</issn><issn>2052-5192</issn><eissn>2052-5206</eissn><abstract>The crystal structure of zharchikhite, AlF(OH)2, from the Zharchikhinskoe deposit (Buryatia, Russia) is solved here using single‐crystal X‐ray diffraction. 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subjects aluminium hydroxyfluoride
aluminofluoride
Apexes
Crystal structure
Lead oxides
Zharchikhinskoe deposit
zharchikhite
α‐PbO2 structure type
title Zharchikhite, AlF(OH)2: a novel structure type related to α‐PbO2
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