Silver Nanowires‐Based Flexible Gold Electrode Overcoming Interior Impedance of Nanomaterial Electrodes

In the development of nanomaterial electrodes for improved electrocatalytic activity, much attention is paid to the compositions, lattice, and surface morphologies. In this study, a new concept to enhance electrocatalytic activity is proposed by reducing impedance inside nanomaterial electrodes. Gold nanodendrites (AuNDs) are grown along silver nanowires (AgNWs) on flexible polydimethylsiloxane (PDMS) support. The AuNDs/AgNWs/PDMS electrode affords an oxidative peak current density of 50 mA cm−2 for ethanol electrooxidation, a value ≈20 times higher than those in the literature do. Electrochemical impedance spectroscopy (EIS) demonstrates the significant contribution of the AgNWs to reduce impedance. The peak current densities for ethanol electrooxidation are decreased 7.5‐fold when the AgNWs are electrolytically corroded. By in situ surface‐enhanced Raman spectroscopy (SERS) and density functional theory (DFT) simulation, it is validated that the ethanol electrooxidation favors the production of acetic acid with undetectable CO, resulting in a more complete oxidation and long‐term stability, while the AgNWs corrosion greatly decreases acetic acid production. This novel strategy for fabricating nanomaterial electrodes using AgNWs as a charge transfer conduit may stimulate insights into the design of nanomaterial electrodes. Gold dendrites built on highly conductive silver nanowires show improved ethanol electrooxidation. Destroying the silver nanowires while leaving the surface gold dendrites unchanged, reduced charge transfer, and impaired electrochemical reaction process are recorded. Rather than experimenting with surface compositions, morphologies, and complexity, it can be an alternative and effective approach to increase interior conductivity for enhanced nanomaterial electrodes.