Synthesis of Core M3 Matriglycan Constituents via an Additive-Controlled 1,2-cis-Xylopyranosylation with O‑Xylosyl Imidates as Donors

A highly stereoselective strategy for 1,2-cis-xylopyranoside bond formation was established via a preactivation-based, additive-modulated trichloroacetimidate glycosidation strategy. The current protocol is mild, practical, and successful with various xylopyranosyl donors and glycosyl acceptors, inc...

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Veröffentlicht in:	Journal of organic chemistry 2024-01, Vol.89 (1), p.804-809
Hauptverfasser:	Li, Tianlu, Zhang, Miaomiao, Lv, Panpan, Yang, Yue, Schmidt, Richard R, Peng, Peng
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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