New Minerals from Inclusions in Corundum Xenocrysts from Mt. Carmel, Israel: Magnéliite, Ziroite, Sassite, Mizraite-(Ce) and Yeite

Our nanomineralogical investigation of melt inclusions in corundum xenocrysts from the Mt. Carmel area, Israel has revealed seven IMA-approved new minerals since 2021. We report here four new oxide minerals and one new alloy mineral. Magnéliite (Ti Ti O ; IMA 2021-111) occurs as subhedral crystals,...

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Veröffentlicht in:Materials 2023-12, Vol.16 (24), p.7578
Hauptverfasser: Ma, Chi, Cámara, Fernando, Bindi, Luca, Toledo, Vered, Griffin, William L
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description Our nanomineralogical investigation of melt inclusions in corundum xenocrysts from the Mt. Carmel area, Israel has revealed seven IMA-approved new minerals since 2021. We report here four new oxide minerals and one new alloy mineral. Magnéliite (Ti Ti O ; IMA 2021-111) occurs as subhedral crystals, ~4 μm in size, with alabandite, zirconolite, Ti,Al,Zr-oxide, and hibonite in corundum Grain 767-1. Magnéliite has an empirical formula (Ti Al Ti Mg Ca Sc ) (Ti Zr ) O and the triclinic 1¯ Ti O -type structure with the cell parameters: = 5.60(1) Å, = 7.13(1) Å, = 12.47(1) Å, = 95.1(1)°, = 95.2(1)°, = 108.7(1)°, = 466(2) Å , = 4. Ziroite (ZrO ; IMA 2022-013) occurs as irregular crystals, ~1-4 μm in size, with baddeleyite, hibonite, and Ti,Al,Zr-oxide in corundum Grain 479-1a. Ziroite has an empirical formula (Zr Ti Mg Al Hf ) O and the tetragonal 4 / zirconia(HT)-type structure with the cell parameters: = 3.60(1) Å, = 5.18(1) Å, = 67.1(3) Å , = 2. Sassite (Ti Ti O ; IMA 2022-014) occurs as subhedral-euhedral crystals, ~4-16 μm in size, with Ti,Al,Zr-oxide, mullite, osbornite, baddeleyite, alabandite, and glass in corundum Grain 1125C1. Sassite has an empirical formula (Ti Al Ti Mg ) (Ti Zr Si ) O and the orthorhombic pseudobrookite-type structure with the cell parameters: = 3.80(1) Å, = 9.85(1) Å, = 9.99(1) Å, = 374(1) Å , = 4. Mizraite-(Ce) (Ce(Al Mg)O ; IMA 2022-027) occurs as euhedral crystals,
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Carmel, Israel: Magnéliite, Ziroite, Sassite, Mizraite-(Ce) and Yeite</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><source>PubMed Central Open Access</source><creator>Ma, Chi ; Cámara, Fernando ; Bindi, Luca ; Toledo, Vered ; Griffin, William L</creator><creatorcontrib>Ma, Chi ; Cámara, Fernando ; Bindi, Luca ; Toledo, Vered ; Griffin, William L</creatorcontrib><description>Our nanomineralogical investigation of melt inclusions in corundum xenocrysts from the Mt. Carmel area, Israel has revealed seven IMA-approved new minerals since 2021. We report here four new oxide minerals and one new alloy mineral. Magnéliite (Ti Ti O ; IMA 2021-111) occurs as subhedral crystals, ~4 μm in size, with alabandite, zirconolite, Ti,Al,Zr-oxide, and hibonite in corundum Grain 767-1. Magnéliite has an empirical formula (Ti Al Ti Mg Ca Sc ) (Ti Zr ) O and the triclinic 1¯ Ti O -type structure with the cell parameters: = 5.60(1) Å, = 7.13(1) Å, = 12.47(1) Å, = 95.1(1)°, = 95.2(1)°, = 108.7(1)°, = 466(2) Å , = 4. Ziroite (ZrO ; IMA 2022-013) occurs as irregular crystals, ~1-4 μm in size, with baddeleyite, hibonite, and Ti,Al,Zr-oxide in corundum Grain 479-1a. Ziroite has an empirical formula (Zr Ti Mg Al Hf ) O and the tetragonal 4 / zirconia(HT)-type structure with the cell parameters: = 3.60(1) Å, = 5.18(1) Å, = 67.1(3) Å , = 2. Sassite (Ti Ti O ; IMA 2022-014) occurs as subhedral-euhedral crystals, ~4-16 μm in size, with Ti,Al,Zr-oxide, mullite, osbornite, baddeleyite, alabandite, and glass in corundum Grain 1125C1. Sassite has an empirical formula (Ti Al Ti Mg ) (Ti Zr Si ) O and the orthorhombic pseudobrookite-type structure with the cell parameters: = 3.80(1) Å, = 9.85(1) Å, = 9.99(1) Å, = 374(1) Å , = 4. Mizraite-(Ce) (Ce(Al Mg)O ; IMA 2022-027) occurs as euhedral crystals, &lt;1-14 μm in size, with Ce-silicate, Ti-sulfide, Ti,Al,Zr-oxide, ziroite, and thorianite in corundum Grain 198-8. Mizraite-(Ce) has an empirical formula (Ce Ca La Nd ) (Al Mg Ti Si Zr ) O and the hexagonal 6 / magnetoplumbite-type structure with the cell parameters: = 5.61(1) Å, = 22.29(1) Å, = 608(2) Å , = 2. Yeite (TiSi; IMA 2022-079) occurs as irregular-subhedral crystals, 1.2-3.5 μm in size, along with wenjiite (Ti Si ) and zhiqinite (TiSi ) in Ti-Si alloy inclusions in corundum Grain 198c. Yeite has an empirical formula (Ti Mn V Cr )(Si P ) and the orthorhombic FeB-type structure with the cell parameters: = 6.55(1) Å, = 3.64(1) Å, = 4.99(1) Å, = 119.0(4) Å , = 4. The five minerals are high-temperature oxide or alloy phases, formed in melt pockets in corundum xenocrysts derived from the upper mantle beneath Mt. Carmel.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma16247578</identifier><identifier>PMID: 38138719</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Aluminum ; Corundum ; Crystal structure ; Crystals ; Electrons ; Heat resistant alloys ; High temperature ; Inclusions ; Mineralogy ; Minerals ; Mullite ; Names ; Parameters ; Registration ; Silicon base alloys ; Titanium ; Volcanoes ; Zirconium dioxide</subject><ispartof>Materials, 2023-12, Vol.16 (24), p.7578</ispartof><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c351t-45aa5e1cd9d5a4a257f19da9ac959b0bf39be1f62bc7df56f627ec3cd22a1a623</citedby><cites>FETCH-LOGICAL-c351t-45aa5e1cd9d5a4a257f19da9ac959b0bf39be1f62bc7df56f627ec3cd22a1a623</cites><orcidid>0000-0002-1828-7033 ; 0000-0003-1168-7306 ; 0000-0002-0980-2566 ; 0000-0001-7768-0946</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38138719$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ma, Chi</creatorcontrib><creatorcontrib>Cámara, Fernando</creatorcontrib><creatorcontrib>Bindi, Luca</creatorcontrib><creatorcontrib>Toledo, Vered</creatorcontrib><creatorcontrib>Griffin, William L</creatorcontrib><title>New Minerals from Inclusions in Corundum Xenocrysts from Mt. Carmel, Israel: Magnéliite, Ziroite, Sassite, Mizraite-(Ce) and Yeite</title><title>Materials</title><addtitle>Materials (Basel)</addtitle><description>Our nanomineralogical investigation of melt inclusions in corundum xenocrysts from the Mt. Carmel area, Israel has revealed seven IMA-approved new minerals since 2021. We report here four new oxide minerals and one new alloy mineral. Magnéliite (Ti Ti O ; IMA 2021-111) occurs as subhedral crystals, ~4 μm in size, with alabandite, zirconolite, Ti,Al,Zr-oxide, and hibonite in corundum Grain 767-1. Magnéliite has an empirical formula (Ti Al Ti Mg Ca Sc ) (Ti Zr ) O and the triclinic 1¯ Ti O -type structure with the cell parameters: = 5.60(1) Å, = 7.13(1) Å, = 12.47(1) Å, = 95.1(1)°, = 95.2(1)°, = 108.7(1)°, = 466(2) Å , = 4. Ziroite (ZrO ; IMA 2022-013) occurs as irregular crystals, ~1-4 μm in size, with baddeleyite, hibonite, and Ti,Al,Zr-oxide in corundum Grain 479-1a. Ziroite has an empirical formula (Zr Ti Mg Al Hf ) O and the tetragonal 4 / zirconia(HT)-type structure with the cell parameters: = 3.60(1) Å, = 5.18(1) Å, = 67.1(3) Å , = 2. Sassite (Ti Ti O ; IMA 2022-014) occurs as subhedral-euhedral crystals, ~4-16 μm in size, with Ti,Al,Zr-oxide, mullite, osbornite, baddeleyite, alabandite, and glass in corundum Grain 1125C1. Sassite has an empirical formula (Ti Al Ti Mg ) (Ti Zr Si ) O and the orthorhombic pseudobrookite-type structure with the cell parameters: = 3.80(1) Å, = 9.85(1) Å, = 9.99(1) Å, = 374(1) Å , = 4. Mizraite-(Ce) (Ce(Al Mg)O ; IMA 2022-027) occurs as euhedral crystals, &lt;1-14 μm in size, with Ce-silicate, Ti-sulfide, Ti,Al,Zr-oxide, ziroite, and thorianite in corundum Grain 198-8. Mizraite-(Ce) has an empirical formula (Ce Ca La Nd ) (Al Mg Ti Si Zr ) O and the hexagonal 6 / magnetoplumbite-type structure with the cell parameters: = 5.61(1) Å, = 22.29(1) Å, = 608(2) Å , = 2. Yeite (TiSi; IMA 2022-079) occurs as irregular-subhedral crystals, 1.2-3.5 μm in size, along with wenjiite (Ti Si ) and zhiqinite (TiSi ) in Ti-Si alloy inclusions in corundum Grain 198c. Yeite has an empirical formula (Ti Mn V Cr )(Si P ) and the orthorhombic FeB-type structure with the cell parameters: = 6.55(1) Å, = 3.64(1) Å, = 4.99(1) Å, = 119.0(4) Å , = 4. The five minerals are high-temperature oxide or alloy phases, formed in melt pockets in corundum xenocrysts derived from the upper mantle beneath Mt. Carmel.</description><subject>Aluminum</subject><subject>Corundum</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Electrons</subject><subject>Heat resistant alloys</subject><subject>High temperature</subject><subject>Inclusions</subject><subject>Mineralogy</subject><subject>Minerals</subject><subject>Mullite</subject><subject>Names</subject><subject>Parameters</subject><subject>Registration</subject><subject>Silicon base alloys</subject><subject>Titanium</subject><subject>Volcanoes</subject><subject>Zirconium dioxide</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkcFO3DAQhi1UBIhy4QGQpV5oRWhsx0nMrYqArrRLD20l4BJNnElllNhgJ0L0ytPwHLwYZlmg6lzmG-nTzEg_IbssPRRCpV8HYDnPClmUa2SLKZUnTGXZh394k-yEcJXGEoKVXG2QTVEyURZMbZH7M7ylC2PRQx9o591AZ1b3UzDOBmosrZyfbDsN9Byt0_4ujCttMR7SCvyA_QGdBQ_YH9EF_LGPD70xIx7QS-PdEn5CCEtYmL8eIiX7FX6mYFt6gXH8SNa7eB13Vn2b_D45_lV9T-Y_TmfVt3mihWRjkkkAiUy3qpWQAZdFx1QLCrSSqkmbTqgGWZfzRhdtJ_NIBWqhW86BQc7FNtl_2Xvt3c2EYawHEzT2PVh0U6i5SqXknBV5VD_9p165ydv43bOVlXleSBmtLy-W9i4Ej1197c0A_q5maf2cTv2eTpT3ViunZsD2TX3NQjwB4qmKbg</recordid><startdate>20231209</startdate><enddate>20231209</enddate><creator>Ma, Chi</creator><creator>Cámara, Fernando</creator><creator>Bindi, Luca</creator><creator>Toledo, Vered</creator><creator>Griffin, William L</creator><general>MDPI AG</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PIMPY</scope><scope>PKEHL</scope><scope>PQEST</scope><scope>PQGLB</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-1828-7033</orcidid><orcidid>https://orcid.org/0000-0003-1168-7306</orcidid><orcidid>https://orcid.org/0000-0002-0980-2566</orcidid><orcidid>https://orcid.org/0000-0001-7768-0946</orcidid></search><sort><creationdate>20231209</creationdate><title>New Minerals from Inclusions in Corundum Xenocrysts from Mt. Carmel, Israel: Magnéliite, Ziroite, Sassite, Mizraite-(Ce) and Yeite</title><author>Ma, Chi ; Cámara, Fernando ; Bindi, Luca ; Toledo, Vered ; Griffin, William L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c351t-45aa5e1cd9d5a4a257f19da9ac959b0bf39be1f62bc7df56f627ec3cd22a1a623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aluminum</topic><topic>Corundum</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Electrons</topic><topic>Heat resistant alloys</topic><topic>High temperature</topic><topic>Inclusions</topic><topic>Mineralogy</topic><topic>Minerals</topic><topic>Mullite</topic><topic>Names</topic><topic>Parameters</topic><topic>Registration</topic><topic>Silicon base alloys</topic><topic>Titanium</topic><topic>Volcanoes</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Chi</creatorcontrib><creatorcontrib>Cámara, Fernando</creatorcontrib><creatorcontrib>Bindi, Luca</creatorcontrib><creatorcontrib>Toledo, Vered</creatorcontrib><creatorcontrib>Griffin, William L</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest Central (New)</collection><collection>ProQuest One Academic (New)</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Middle East (New)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Applied &amp; Life Sciences</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>MEDLINE - Academic</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Chi</au><au>Cámara, Fernando</au><au>Bindi, Luca</au><au>Toledo, Vered</au><au>Griffin, William L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New Minerals from Inclusions in Corundum Xenocrysts from Mt. Carmel, Israel: Magnéliite, Ziroite, Sassite, Mizraite-(Ce) and Yeite</atitle><jtitle>Materials</jtitle><addtitle>Materials (Basel)</addtitle><date>2023-12-09</date><risdate>2023</risdate><volume>16</volume><issue>24</issue><spage>7578</spage><pages>7578-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>Our nanomineralogical investigation of melt inclusions in corundum xenocrysts from the Mt. Carmel area, Israel has revealed seven IMA-approved new minerals since 2021. We report here four new oxide minerals and one new alloy mineral. Magnéliite (Ti Ti O ; IMA 2021-111) occurs as subhedral crystals, ~4 μm in size, with alabandite, zirconolite, Ti,Al,Zr-oxide, and hibonite in corundum Grain 767-1. Magnéliite has an empirical formula (Ti Al Ti Mg Ca Sc ) (Ti Zr ) O and the triclinic 1¯ Ti O -type structure with the cell parameters: = 5.60(1) Å, = 7.13(1) Å, = 12.47(1) Å, = 95.1(1)°, = 95.2(1)°, = 108.7(1)°, = 466(2) Å , = 4. Ziroite (ZrO ; IMA 2022-013) occurs as irregular crystals, ~1-4 μm in size, with baddeleyite, hibonite, and Ti,Al,Zr-oxide in corundum Grain 479-1a. Ziroite has an empirical formula (Zr Ti Mg Al Hf ) O and the tetragonal 4 / zirconia(HT)-type structure with the cell parameters: = 3.60(1) Å, = 5.18(1) Å, = 67.1(3) Å , = 2. Sassite (Ti Ti O ; IMA 2022-014) occurs as subhedral-euhedral crystals, ~4-16 μm in size, with Ti,Al,Zr-oxide, mullite, osbornite, baddeleyite, alabandite, and glass in corundum Grain 1125C1. Sassite has an empirical formula (Ti Al Ti Mg ) (Ti Zr Si ) O and the orthorhombic pseudobrookite-type structure with the cell parameters: = 3.80(1) Å, = 9.85(1) Å, = 9.99(1) Å, = 374(1) Å , = 4. Mizraite-(Ce) (Ce(Al Mg)O ; IMA 2022-027) occurs as euhedral crystals, &lt;1-14 μm in size, with Ce-silicate, Ti-sulfide, Ti,Al,Zr-oxide, ziroite, and thorianite in corundum Grain 198-8. Mizraite-(Ce) has an empirical formula (Ce Ca La Nd ) (Al Mg Ti Si Zr ) O and the hexagonal 6 / magnetoplumbite-type structure with the cell parameters: = 5.61(1) Å, = 22.29(1) Å, = 608(2) Å , = 2. Yeite (TiSi; IMA 2022-079) occurs as irregular-subhedral crystals, 1.2-3.5 μm in size, along with wenjiite (Ti Si ) and zhiqinite (TiSi ) in Ti-Si alloy inclusions in corundum Grain 198c. Yeite has an empirical formula (Ti Mn V Cr )(Si P ) and the orthorhombic FeB-type structure with the cell parameters: = 6.55(1) Å, = 3.64(1) Å, = 4.99(1) Å, = 119.0(4) Å , = 4. The five minerals are high-temperature oxide or alloy phases, formed in melt pockets in corundum xenocrysts derived from the upper mantle beneath Mt. Carmel.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>38138719</pmid><doi>10.3390/ma16247578</doi><orcidid>https://orcid.org/0000-0002-1828-7033</orcidid><orcidid>https://orcid.org/0000-0003-1168-7306</orcidid><orcidid>https://orcid.org/0000-0002-0980-2566</orcidid><orcidid>https://orcid.org/0000-0001-7768-0946</orcidid><oa>free_for_read</oa></addata></record>
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subjects Aluminum
Corundum
Crystal structure
Crystals
Electrons
Heat resistant alloys
High temperature
Inclusions
Mineralogy
Minerals
Mullite
Names
Parameters
Registration
Silicon base alloys
Titanium
Volcanoes
Zirconium dioxide
title New Minerals from Inclusions in Corundum Xenocrysts from Mt. Carmel, Israel: Magnéliite, Ziroite, Sassite, Mizraite-(Ce) and Yeite
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