Isotopomer fractionation in the UV photolysis of N2O: Comparison of theory and experiment

In the photodissociation of N2O, absorption cross sections differ with isotopic substitution, leading to a wavelength‐dependent fractionation of the various isotopomers. Several models ranging from shifts by zero‐point energy differences to propagation of wave packets on the excited electronic state...

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Veröffentlicht in:Journal of Geophysical Research. D. Atmospheres 2005-11, Vol.110 (D21), p.D21315.1-n/a
Hauptverfasser: Prakash, Meher K., Weibel, Jason D., Marcus, R. A.
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Sprache:eng
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