Mono(Lewis Base)‐Stabilized Gallium Iodide: An Unexplored Class of Promising Ligands

Quantum‐chemical (DFT) calculations on hitherto unknown base(carbene)‐stabilized gallium monoiodides (LB→GaI) suggest that these systems feature one lone pair of electrons and a formally vacant p‐orbital – both centered at the central gallium atom – and exhibit metallomimetic behavior. The calculate...

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Veröffentlicht in:	Chemistry : a European journal 2024-03, Vol.30 (13), p.e202303746-n/a
Hauptverfasser:	Ahmed, Sahtaz, Das, Himashri, González‐Pinardo, Daniel, Fernández, Israel, Phukan, Ashwini K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene Carbenes Chemical bonds Chlorides C−H Activation Decomposition reactions Gallium Gallium monoiodide Iodides Lewis base Ligands Metallomimetic Nickel Silane Transition metals
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