Synthesis and Photophysical Properties of Silole-Fused Cycloparaphenylenes

Synthesis and Photophysical Properties of Silole-Fused Cycloparaphenylenes

Herein, we report the introduction of a silole unit into cycloparaphenylenes (CPPs), and two compounds [12]­Si 3 CPP and [16]­Si 4 CPP are obtained by a platinum- and gold-mediated cyclooligomerization strategy. Their optical and electronic properties are studied by UV–vis absorption and fluorescenc...

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Veröffentlicht in:Journal of organic chemistry 2024-01, Vol.89 (1), p.681-686
Hauptverfasser: Wang, Yedong, Huang, Shiqing, Zhang, Zengyu, Yan, Xiaoyu
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container_title Journal of organic chemistry
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creator Wang, Yedong
Huang, Shiqing
Zhang, Zengyu
Yan, Xiaoyu
description Herein, we report the introduction of a silole unit into cycloparaphenylenes (CPPs), and two compounds [12]­Si 3 CPP and [16]­Si 4 CPP are obtained by a platinum- and gold-mediated cyclooligomerization strategy. Their optical and electronic properties are studied by UV–vis absorption and fluorescence spectra, which show red shifts and higher photoluminescence quantum yields (PLQYs) compared with the corresponding CPPs.
doi_str_mv 10.1021/acs.joc.3c01323
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title Synthesis and Photophysical Properties of Silole-Fused Cycloparaphenylenes
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