Metal‐Free 1,3‐Boronate Rearrangement to Ketones Driven by Visible Light

Boronate rearrangements, such as the Matteson and Petasis reactions, are valuable metal‐free reactions for the transfer of the carbo group on boron to intramolecular electrophilic sites. However, only highly reactive electrophiles are suitable, and ketones are too inactive for those boronate rearran...

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Veröffentlicht in:	Angewandte Chemie International Edition 2024-01, Vol.63 (4), p.e202316481-n/a
Hauptverfasser:	Hao, Kejia, Li, Defang, Fu, Dongmin, Zou, Peng, Xie, Shasha, Lan, Yu, Chen, Yiyun
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Boron Complex formation Diketones Free radicals Intermediates Irradiation Ketones Light irradiation Photochemistry Reaction Mechanisms Rearrangements Substrates
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