Application of Metal-Based Catalysts for Semi-Hydrogenation of Alkynol: A Review
Alkynol semi-hydrogenation plays a vital role in industrial processes, due to the significance of its main product, enol, in high-end chemical synthesis, such as medicine, pesticide, food additives, and polymer monomer synthesis. Multiple intermediates are formed through a complex series of parallel...
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| Veröffentlicht in: | Materials 2023-11, Vol.16 (23), p.7409 |
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| creator | Wang, Pengxian Ma, Yue Shi, Yiran Duan, Fangying Wang, Meng |
| description | Alkynol semi-hydrogenation plays a vital role in industrial processes, due to the significance of its main product, enol, in high-end chemical synthesis, such as medicine, pesticide, food additives, and polymer monomer synthesis. Multiple intermediates are formed through a complex series of parallel or continuous reactions under varying conditions. However, the selectivity and efficiency of catalysts for producing these products still pose significant challenges. This review aims to thoroughly discuss the challenges and advancements in catalysts using different species and supports under various reaction conditions. Furthermore, strategies to enhance the yield and rate of enols are summarized based on noble metals, non-noble metals, and metal comparisons. By addressing diverse catalysts and reaction conditions, this review provides valuable insights into improving the semi-hydrogenation of acetylenic alcohols to enols. |
| doi_str_mv | 10.3390/ma16237409 |
| format | Article |
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Multiple intermediates are formed through a complex series of parallel or continuous reactions under varying conditions. However, the selectivity and efficiency of catalysts for producing these products still pose significant challenges. This review aims to thoroughly discuss the challenges and advancements in catalysts using different species and supports under various reaction conditions. Furthermore, strategies to enhance the yield and rate of enols are summarized based on noble metals, non-noble metals, and metal comparisons. By addressing diverse catalysts and reaction conditions, this review provides valuable insights into improving the semi-hydrogenation of acetylenic alcohols to enols.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma16237409</identifier><identifier>PMID: 38068153</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Alcohol ; Alcohols ; Carbon ; Catalysis ; Catalysts ; Chemical bonds ; Chemical synthesis ; Comparative analysis ; Electrocatalysis ; Energy consumption ; Enols ; Food additives ; Heavy metals ; Hydrogen ; Hydrogenation ; Metal industry ; Nanoparticles ; Noble metals ; Poisoning ; Poisons ; Precious metals ; Production processes</subject><ispartof>Materials, 2023-11, Vol.16 (23), p.7409</ispartof><rights>COPYRIGHT 2023 MDPI AG</rights><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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| subjects | Alcohol Alcohols Carbon Catalysis Catalysts Chemical bonds Chemical synthesis Comparative analysis Electrocatalysis Energy consumption Enols Food additives Heavy metals Hydrogen Hydrogenation Metal industry Nanoparticles Noble metals Poisoning Poisons Precious metals Production processes |
| title | Application of Metal-Based Catalysts for Semi-Hydrogenation of Alkynol: A Review |
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