Total organic carbon concentrations in clastic cave sediments from Butler Cave, Virginia, USA: implications for contaminant fate and transport
Clastic cave deposits are representative of sediments throughout the karst aquifer and are an abundant and accessible resource through which to study the sediment chemistry of karst aquifers. Clastic cave sediments are attributed to depositional facies based on location, sorting, and particle size....
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| Veröffentlicht in: | Environmental earth sciences 2023-05, Vol.82 (9), p.231-231, Article 231 |
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| creator | Riddell, Jill L. Downey, Autum R. Vesper, Dorothy J. Padilla, Ingrid Y. |
| description | Clastic cave deposits are representative of sediments throughout the karst aquifer and are an abundant and accessible resource through which to study the sediment chemistry of karst aquifers. Clastic cave sediments are attributed to depositional facies based on location, sorting, and particle size. These facies settings may influence different chemical parameters of the sediments, like concentrations of total organic carbon (TOC). The TOC concentrations in clastic cave sediments have not been well constrained nor has the role of clastic sediments in contaminant fate and transport through karst systems been well described. In this study, particle size, TOC, and total nitrogen were measured in sediments representing different facies in Butler Cave, Virginia, USA. TOC concentrations ranged from 0.08 to 0.87 weight percent and C:N molar ratio ranged from 3 to 15, indicating a possible terrestrial source of organic carbon in these sediments. Samples from diamicton facies were sandier and had similar TOC concentrations compared to samples from channel facies. TOC concentrations measured in Butler Cave were within the same range as those observed in more above water, eogenetic clastic cave sediments from two caves in Puerto Rico. Estimated retardation factors calculated based on the TOC concentrations in the Butler Cave sediments indicate the range of TOC in this cave could be responsible for 39–987% increase in retardation of selected contaminants. This study highlights the importance of measuring the ranges of TOC in clastic cave sediments across different facies and their role in contaminant fate and transport. |
| doi_str_mv | 10.1007/s12665-023-10893-4 |
| format | Article |
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TOC concentrations measured in Butler Cave were within the same range as those observed in more above water, eogenetic clastic cave sediments from two caves in Puerto Rico. Estimated retardation factors calculated based on the TOC concentrations in the Butler Cave sediments indicate the range of TOC in this cave could be responsible for 39–987% increase in retardation of selected contaminants. 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Clastic cave sediments are attributed to depositional facies based on location, sorting, and particle size. These facies settings may influence different chemical parameters of the sediments, like concentrations of total organic carbon (TOC). The TOC concentrations in clastic cave sediments have not been well constrained nor has the role of clastic sediments in contaminant fate and transport through karst systems been well described. In this study, particle size, TOC, and total nitrogen were measured in sediments representing different facies in Butler Cave, Virginia, USA. TOC concentrations ranged from 0.08 to 0.87 weight percent and C:N molar ratio ranged from 3 to 15, indicating a possible terrestrial source of organic carbon in these sediments. Samples from diamicton facies were sandier and had similar TOC concentrations compared to samples from channel facies. TOC concentrations measured in Butler Cave were within the same range as those observed in more above water, eogenetic clastic cave sediments from two caves in Puerto Rico. Estimated retardation factors calculated based on the TOC concentrations in the Butler Cave sediments indicate the range of TOC in this cave could be responsible for 39–987% increase in retardation of selected contaminants. This study highlights the importance of measuring the ranges of TOC in clastic cave sediments across different facies and their role in contaminant fate and transport.</description><subject>Aquifers</subject><subject>Biogeosciences</subject><subject>Carbon</subject><subject>Carbon content</subject><subject>Caves</subject><subject>Contaminants</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>environmental fate</subject><subject>Environmental Science and Engineering</subject><subject>Geochemistry</subject><subject>Geology</subject><subject>Hydrology/Water Resources</subject><subject>Karst</subject><subject>karsts</subject><subject>Mathematical analysis</subject><subject>Organic carbon</subject><subject>Original Article</subject><subject>Particle size</subject><subject>Puerto Rico</subject><subject>Sediment</subject><subject>Sediment chemistry</subject><subject>Sediment deposits</subject><subject>Sediment samples</subject><subject>Sedimentary facies</subject><subject>Sediments</subject><subject>Terrestrial Pollution</subject><subject>total nitrogen</subject><subject>Total organic carbon</subject><subject>Transport</subject><subject>Virginia</subject><issn>1866-6280</issn><issn>1866-6299</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNqFkU1PHCEYx4mpqUb9Ah4MSS89OJW3nR16003fEpMeql4JAw8bzAyswJj4JfqZy7hbm3ioXHh5_vyewA-hU0o-UUKWF5mytl00hPGGkk7yRuyhQ9q1bdMyKd-9rDtygE5yvid1cMolad-jA96RZUclO0S_b2LRA45prYM32OjUx4BNDAZCSbr4GDL29WTQuTwHHgFnsH6s9YxdiiO-msoACa9q6Rzf-bT2wetzfPvr8jP242bwZsdxMc3ookcfdCjY6QJYB4trp5A3MZVjtO_0kOFkNx-h269fblbfm-uf336sLq8bLVhbGuO0dc721DK7AGGZNpbquu-ccD1ICoxKZ4XjHMBxaZZuKag0Eqzta5UfoY9b7ibFhwlyUaPPBoZBB4hTVpwuOBUdF-TNKJOEyflDRY1-eBW9j1MK9SGqeqguuFzMQLZNmRRzTuDUJvlRpydFiZrdqq1bVd2qZ7dqRp_t0FM_gn258tdkDfBtINdSWEP61_s_2D8ZCbIL</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Riddell, Jill L.</creator><creator>Downey, Autum R.</creator><creator>Vesper, Dorothy J.</creator><creator>Padilla, Ingrid Y.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7TG</scope><scope>7UA</scope><scope>7XB</scope><scope>88I</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>H96</scope><scope>HCIFZ</scope><scope>KL.</scope><scope>L.G</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>SOI</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0002-2096-7548</orcidid><orcidid>https://orcid.org/0000-0001-8460-1679</orcidid><orcidid>https://orcid.org/0000-0003-3485-2896</orcidid><orcidid>https://orcid.org/0000-0002-8050-799X</orcidid><orcidid>https://orcid.org/0000-0002-2960-7548</orcidid></search><sort><creationdate>20230501</creationdate><title>Total organic carbon concentrations in clastic cave sediments from Butler Cave, Virginia, USA: implications for contaminant fate and transport</title><author>Riddell, Jill L. ; 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TOC concentrations measured in Butler Cave were within the same range as those observed in more above water, eogenetic clastic cave sediments from two caves in Puerto Rico. Estimated retardation factors calculated based on the TOC concentrations in the Butler Cave sediments indicate the range of TOC in this cave could be responsible for 39–987% increase in retardation of selected contaminants. 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| subjects | Aquifers Biogeosciences Carbon Carbon content Caves Contaminants Earth and Environmental Science Earth Sciences environmental fate Environmental Science and Engineering Geochemistry Geology Hydrology/Water Resources Karst karsts Mathematical analysis Organic carbon Original Article Particle size Puerto Rico Sediment Sediment chemistry Sediment deposits Sediment samples Sedimentary facies Sediments Terrestrial Pollution total nitrogen Total organic carbon Transport Virginia |
| title | Total organic carbon concentrations in clastic cave sediments from Butler Cave, Virginia, USA: implications for contaminant fate and transport |
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