Preparation of boron carbon nitride thin films by radio frequency magnetron sputtering

Boron carbon nitride films were deposited by radio frequency magnetron sputtering using a composite target consisting of h-BN and graphite in an Ar–N 2 gas mixture. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The...

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Veröffentlicht in:Applied surface science 2006-04, Vol.252 (12), p.4185-4189
Hauptverfasser: Liu, Lihua, Wang, Yuxin, Feng, Kecheng, Li, Yingai, Li, Weiqing, Zhao, Chunhong, Zhao, Yongnian
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container_end_page 4189
container_issue 12
container_start_page 4185
container_title Applied surface science
container_volume 252
creator Liu, Lihua
Wang, Yuxin
Feng, Kecheng
Li, Yingai
Li, Weiqing
Zhao, Chunhong
Zhao, Yongnian
description Boron carbon nitride films were deposited by radio frequency magnetron sputtering using a composite target consisting of h-BN and graphite in an Ar–N 2 gas mixture. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The results suggest that the films are atomic-level hybrids composed of B, C and N atoms. The boron carbon nitride films prepared in the present experiment have a disordered structure. The sputtering power varied from 80 W to 130 W. This sputtering power was shown to have regular effect on the composition of boron carbon nitride films. The samples deposited at 80 W and 130 W are close to the stoichiometry of BC 3N. The sample deposited at 110 W is close to the stoichiometry of BCN. The samples deposited at 100 W and 120 W approach to BC 2N. It is very significant for us to synthesize boron carbon nitride compound with controllable composition by changing the sputtering power.
doi_str_mv 10.1016/j.apsusc.2005.06.025
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The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The results suggest that the films are atomic-level hybrids composed of B, C and N atoms. The boron carbon nitride films prepared in the present experiment have a disordered structure. The sputtering power varied from 80 W to 130 W. This sputtering power was shown to have regular effect on the composition of boron carbon nitride films. The samples deposited at 80 W and 130 W are close to the stoichiometry of BC 3N. The sample deposited at 110 W is close to the stoichiometry of BCN. The samples deposited at 100 W and 120 W approach to BC 2N. It is very significant for us to synthesize boron carbon nitride compound with controllable composition by changing the sputtering power.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.apsusc.2005.06.025</doi><tpages>5</tpages></addata></record>
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subjects Boron carbon nitride thin films
Cross-disciplinary physics: materials science
rheology
Deposition by sputtering
Exact sciences and technology
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Physics
Radio frequency magnetron sputtering
title Preparation of boron carbon nitride thin films by radio frequency magnetron sputtering
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