Boryl radical catalysis enables asymmetric radical cycloisomerization reactions

The development of functionally distinct catalysts for enantioselective synthesis is a prominent yet challenging goal of synthetic chemistry. In this work, we report a family of chiral N -heterocyclic carbene (NHC)–ligated boryl radicals as catalysts that enable catalytic asymmetric radical cycloiso...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2023-12, Vol.382 (6674), p.1056-1065
Hauptverfasser:	Wang, Chang-Ling, Wang, Jie, Jin, Ji-Kang, Li, Bin, Phang, Yee Lin, Zhang, Feng-Lian, Ye, Tian, Xia, Hui-Min, Hui, Li-Wen, Su, Ji-Hu, Fu, Yao, Wang, Yi-Feng
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Asymmetry Boron Catalysis Catalysts Isomerization
Online-Zugang:	Volltext
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