Viscous Flow as the Driving Force for the Densification of Low-Temperature Co-Fired Ceramics

Filled glass–ceramic composites, like low‐temperature co‐fired ceramics (LTCC), must densify at temperatures

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Veröffentlicht in:Journal of the American Ceramic Society 2007-01, Vol.90 (1), p.64-70
Hauptverfasser: Kemethmüller, Stefan, Hagymasi, Marcel, Stiegelschmitt, Alfons, Roosen, Andreas
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container_issue 1
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container_title Journal of the American Ceramic Society
container_volume 90
creator Kemethmüller, Stefan
Hagymasi, Marcel
Stiegelschmitt, Alfons
Roosen, Andreas
description Filled glass–ceramic composites, like low‐temperature co‐fired ceramics (LTCC), must densify at temperatures
doi_str_mv 10.1111/j.1551-2916.2006.01362.x
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The densification mechanism of LTCC is often described by liquid‐phase sintering. The results of this paper clearly show that densification of ceramic‐filled glass–composites with a glass content above 60 wt% can be attributed to viscous sintering, which is decisively controlled by the viscosity of the glass during the heat treatment. This is demonstrated by the experimental determination of the viscosity of a MgO–Al2O3–B2O3–SiO2 glass dependent on temperature, by investigation of the wetting behavior of the glass on the ceramic filler mullite, and of the microstructural development. It was found that the glass does not wet the filler material in a temperature range up to 1000°C. Therefore, liquid‐phase sintering can be excluded. Independent of any wetting effect and therefore in the absence of capillary forces, densification starts at a temperature of 750°C, which corresponds to a viscosity of 109.5 dPa·s. 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The densification mechanism of LTCC is often described by liquid‐phase sintering. The results of this paper clearly show that densification of ceramic‐filled glass–composites with a glass content above 60 wt% can be attributed to viscous sintering, which is decisively controlled by the viscosity of the glass during the heat treatment. This is demonstrated by the experimental determination of the viscosity of a MgO–Al2O3–B2O3–SiO2 glass dependent on temperature, by investigation of the wetting behavior of the glass on the ceramic filler mullite, and of the microstructural development. It was found that the glass does not wet the filler material in a temperature range up to 1000°C. Therefore, liquid‐phase sintering can be excluded. Independent of any wetting effect and therefore in the absence of capillary forces, densification starts at a temperature of 750°C, which corresponds to a viscosity of 109.5 dPa·s. 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The densification mechanism of LTCC is often described by liquid‐phase sintering. The results of this paper clearly show that densification of ceramic‐filled glass–composites with a glass content above 60 wt% can be attributed to viscous sintering, which is decisively controlled by the viscosity of the glass during the heat treatment. This is demonstrated by the experimental determination of the viscosity of a MgO–Al2O3–B2O3–SiO2 glass dependent on temperature, by investigation of the wetting behavior of the glass on the ceramic filler mullite, and of the microstructural development. It was found that the glass does not wet the filler material in a temperature range up to 1000°C. Therefore, liquid‐phase sintering can be excluded. Independent of any wetting effect and therefore in the absence of capillary forces, densification starts at a temperature of 750°C, which corresponds to a viscosity of 109.5 dPa·s. This densification can be attributed to viscous flow of the glass matrix composite.</abstract><cop>Malden, USA</cop><pub>Blackwell Publishing Inc</pub><doi>10.1111/j.1551-2916.2006.01362.x</doi><tpages>7</tpages></addata></record>
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subjects Applied sciences
Building materials. Ceramics. Glasses
Ceramic industries
Ceramic matrix composites
Ceramic sintering
Chemical industry and chemicals
Densification
Exact sciences and technology
Experiments
Glass-ceramics
Glasses
Miscellaneous
Technical ceramics
Temperature effects
Viscosity
title Viscous Flow as the Driving Force for the Densification of Low-Temperature Co-Fired Ceramics
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