Vitamin B12‐Photocatalyzed Cyclopropanation of Electron‐Deficient Alkenes Using Dichloromethane as the Methylene Source

The cyclopropyl group is of great importance in medicinal chemistry, as it can be leveraged to influence a range of pharmaceutical properties in drug molecules. This report describes a Vitamin B12‐photocatalyzed approach for the cyclopropanation of electron‐deficient alkenes using dichloromethane (C...

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Veröffentlicht in:	Angewandte Chemie International Edition 2024-01, Vol.63 (2), p.e202316064-n/a
Hauptverfasser:	Teye‐Kau, John Hayford G., Ayodele, Mayokun J., Pitre, Spencer P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Alkenes Cobalt Cyanocobalamin Cyclopropanation Dichloroethane Dichloromethane Functional groups Organic compounds Photocatalysis Radicals Visible Light Vitamin B12
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