Recent advances in ring-opening of cyclobutanone oximes for capturing SO2, CO or O2via a radical process

Cyclobutanone oximes and their derivatives are pivotal core structural motifs in organic chemistry. Iminyl-radical-triggered C–C bond cleavage of cyclobutanone oximes delivers an efficient strategy to produce stable distal cyano-substituted alkyl radicals, which can capture SO2, CO or O2 to form cya...

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Veröffentlicht in:	Organic & biomolecular chemistry 2023-12, Vol.22 (1), p.10-24
Hauptverfasser:	Long-Jin, Zhong, Jian-Hong, Fan, Chen, Pu, Peng-Fei, Huang, Bi-Quan Xiong, Ke-Wen, Tang, Liu, Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Covalent bonds Organic chemistry Oximes Radicals Ring opening Sulfur dioxide Sulfur dioxide recovery
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creator	Long-Jin, Zhong Jian-Hong, Fan Chen, Pu Peng-Fei, Huang Bi-Quan Xiong Ke-Wen, Tang Liu, Yu
description	Cyclobutanone oximes and their derivatives are pivotal core structural motifs in organic chemistry. Iminyl-radical-triggered C–C bond cleavage of cyclobutanone oximes delivers an efficient strategy to produce stable distal cyano-substituted alkyl radicals, which can capture SO2, CO or O2 to form cyanoalkylsulfonyl radicals, cyanoalkylcarbonyl radicals or cyanoalkoxyl radicals under mild conditions. In the past several years, cyanoalkylsulfonylation/cyanoalkylcarbonyaltion/cyanoalkoxylation has attracted a lot of interest. In this updated report, the strategies for trapping SO2, CO or O2via iminyl-radical-triggered ring-opening of cyclobutanone oximes are summarized.
doi_str_mv	10.1039/d3ob01762a
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subjects	Covalent bonds Organic chemistry Oximes Radicals Ring opening Sulfur dioxide Sulfur dioxide recovery
title	Recent advances in ring-opening of cyclobutanone oximes for capturing SO2, CO or O2via a radical process
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