A Raman spectroscopic and ab initio investigation of aqueous boron speciation under alkaline hydrothermal conditions: evidence for the structure and thermodynamic stability of the diborate ion

Raman spectra of aqueous sodium borate solutions, with and without excess NaOH, NaCl, and LiCl, have been obtained from perpendicular and parallel polarization measurements acquired using a custom-built sapphire flow cell over the temperature range 25 to 300 °C at 20 MPa. The solvent-corrected reduc...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2023-12, Vol.52 (48), p.18391-18406
Hauptverfasser: Sasidharanpillai, Swaroop, Cox, Jenny S, Pye, Cory C, Tremaine, Peter R
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Sprache:eng
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