Evaluation of inorganic adsorbents for the removal of problematic textile dyes and pesticides
Activated bauxite, Fullers earth and a synthetic hydrotalcite clay were compared with activated carbon for the removal of reactive dyes, pentachlorophenol and Propetamphos, which were contaminants of major concern in the U.K. textile industry. Thermogravimetric analyses indicated that bauxite and Fu...
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Veröffentlicht in: | Water science and technology 1997, Vol.36 (2-3), p.173-180 |
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creator | LAMBERT, S. D GRAHAM, N. J. D SOLLARS, C. J FOWLER, G. D |
description | Activated bauxite, Fullers earth and a synthetic hydrotalcite clay were compared with activated carbon for the removal of reactive dyes, pentachlorophenol and Propetamphos, which were contaminants of major concern in the U.K. textile industry. Thermogravimetric analyses indicated that bauxite and Fullers earth were best calcined at 700C before use and that the clay required no heat treatment. All the adsorbents were then chemically conditioned before their capacities were measured by batch adsorption tests. Residual dye was measured by spectrophotometry; the pesticides were analysed by high performance liquid chromatography. Synthetic clay removed reactive dyes most effectively at pH 5.5-8.5 and 20-40C; activated carbon performed comparably under neutral and alkaline conditions. Bauxite was as effective as activated carbon under acidic conditions, while Fullers earth was ineffective. Only activated carbon removed the pesticides to any degree. |
doi_str_mv | 10.1016/S0273-1223(97)00385-5 |
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D ; GRAHAM, N. J. D ; SOLLARS, C. J ; FOWLER, G. D</creator><contributor>Andreadakis, A</contributor><creatorcontrib>LAMBERT, S. D ; GRAHAM, N. J. D ; SOLLARS, C. J ; FOWLER, G. D ; Andreadakis, A</creatorcontrib><description>Activated bauxite, Fullers earth and a synthetic hydrotalcite clay were compared with activated carbon for the removal of reactive dyes, pentachlorophenol and Propetamphos, which were contaminants of major concern in the U.K. textile industry. Thermogravimetric analyses indicated that bauxite and Fullers earth were best calcined at 700C before use and that the clay required no heat treatment. All the adsorbents were then chemically conditioned before their capacities were measured by batch adsorption tests. Residual dye was measured by spectrophotometry; the pesticides were analysed by high performance liquid chromatography. Synthetic clay removed reactive dyes most effectively at pH 5.5-8.5 and 20-40C; activated carbon performed comparably under neutral and alkaline conditions. Bauxite was as effective as activated carbon under acidic conditions, while Fullers earth was ineffective. 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Synthetic clay removed reactive dyes most effectively at pH 5.5-8.5 and 20-40C; activated carbon performed comparably under neutral and alkaline conditions. Bauxite was as effective as activated carbon under acidic conditions, while Fullers earth was ineffective. Only activated carbon removed the pesticides to any degree.</description><subject>Activated carbon</subject><subject>Activated clay</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Agrochemicals</subject><subject>Aluminum base alloys</subject><subject>Applied sciences</subject><subject>Bauxite</subject><subject>Bayer process</subject><subject>Carbon</subject><subject>Clay</subject><subject>Color removal</subject><subject>Contaminants</subject><subject>Dyes</subject><subject>Earth</subject><subject>Effluents</subject><subject>Evaluation</subject><subject>Exact sciences and technology</subject><subject>Fullers earth</subject><subject>Industrial wastewaters</subject><subject>Pentachlorophenol</subject><subject>Pesticides</subject><subject>pH effects</subject><subject>Pollutant removal</subject><subject>Pollution</subject><subject>Removal</subject><subject>Textile industry</subject><subject>Textile industry wastes</subject><subject>Wastewaters</subject><subject>Water treatment and pollution</subject><issn>0273-1223</issn><issn>1996-9732</issn><isbn>0080433715</isbn><isbn>9780080433714</isbn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNqFkc9rFTEQx4M_wNfqnyAEFNHD6iSTzSRHKbUVCh7Uo4RsktUt-zbPZJ_Y_968tvTg5Z0Ghs93ZpgPYy8FvBcg9IevIAk7ISW-tfQOAE3f9Y_YRlirO0soH7MTAAMKkUT_hG0e-GfspNZrACBUsGE_zv_4ee_XKS88j3xacvnplylwH2suQ1rWysdc-Por8ZK2udEHblfyMKdtywW-pr_rNCceb1Llfol8l2rrTzHV5-zp6OeaXtzXU_b90_m3s8vu6svF57OPV11Aq_pORG-MpEH2KoCIhFHhoFGGQH4wNklsnWSDiSFIkiQiBjFSGEE22gs8ZW_u5ra7fu_beredakjz7JeU99VJY1GQgqOg0JIMkToOKqW1NsdXC9QSBNgGvvoPvM77srS3OGGbJ616Q43q76hQcq0ljW5Xpq0vN06AO6h3t-rdQaWz5G7Vu77lXt9P9zX4eSx-CVN9CEtATdbiP6Zbq1M</recordid><startdate>1997</startdate><enddate>1997</enddate><creator>LAMBERT, S. 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subjects | Activated carbon Activated clay Adsorbents Adsorption Agrochemicals Aluminum base alloys Applied sciences Bauxite Bayer process Carbon Clay Color removal Contaminants Dyes Earth Effluents Evaluation Exact sciences and technology Fullers earth Industrial wastewaters Pentachlorophenol Pesticides pH effects Pollutant removal Pollution Removal Textile industry Textile industry wastes Wastewaters Water treatment and pollution |
title | Evaluation of inorganic adsorbents for the removal of problematic textile dyes and pesticides |
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