Two Stable Bifunctional Zinc Metal–Organic Frameworks with Luminescence Detection of Antibiotics and Proton Conduction

Functionalized crystalline solids based on metal–organic frameworks (MOFs) enable efficient luminescence detection and high proton conductivity, making them crucial in the realms of environmental monitoring and clean energy. Here, two structurally and functionally distinct zinc-based MOFs, [Zn­(TTDP...

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Veröffentlicht in:Inorganic chemistry 2023-12, Vol.62 (49), p.20314-20324
Hauptverfasser: Mu, Zhi-Lin, Ma, Yi-Qing, Zhu, Yibin, Chen, Zhongyan, Xiao, Hong-Ping, Li, Xinhua, Wang, Hai-Ying, Ge, Jing-Yuan
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container_end_page 20324
container_issue 49
container_start_page 20314
container_title Inorganic chemistry
container_volume 62
creator Mu, Zhi-Lin
Ma, Yi-Qing
Zhu, Yibin
Chen, Zhongyan
Xiao, Hong-Ping
Li, Xinhua
Wang, Hai-Ying
Ge, Jing-Yuan
description Functionalized crystalline solids based on metal–organic frameworks (MOFs) enable efficient luminescence detection and high proton conductivity, making them crucial in the realms of environmental monitoring and clean energy. Here, two structurally and functionally distinct zinc-based MOFs, [Zn­(TTDPa)­(bodca)]·H2O (1) and [Zn­(TTDPb)­(bodca)]·H2O (2), were successfully designed and synthesized using 3,6-di­(pyridin-4-yl)­thieno­[3,2-b]­thiophene (TTDPa) and 2,5-di­(pyridin-4-yl)­thieno­[3,2-b]­thiophene (TTDPb) as ligands, in the presence of bicyclo[2.2.2]­octane-1,4-dicarboxylic acid (H2bodca). Both 1 and 2 display a three-dimensional (3D) structure with 5-fold interpenetration, and notably, 2 forms a larger one-dimensional pore measuring 17.16 × 10.81 Å2 in size. Fluorescence experiments demonstrate that 1 and 2 can function as luminescent sensors for nitrofurantoin (NFT) and nitrofurazone (NFZ) with low detection limits, remarkable selectivity, and good recyclability. A comprehensive analysis was conducted to investigate the differing sensing effects of compounds 1 and 2 and to explore potential sensing mechanisms. Additionally, at 328 K and 98% relative humidity, 1 and 2 exhibit proton conductivity values of 2.13 × 10–3 and 4.91 × 10–3 S cm–1, respectively, making them suitable proton-conducting materials. Hence, the integration of luminescent sensing and proton conductivity in monophasic 3D Zn-MOFs holds significant potential for application in intelligent multitasking devices.
doi_str_mv 10.1021/acs.inorgchem.3c03315
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Here, two structurally and functionally distinct zinc-based MOFs, [Zn­(TTDPa)­(bodca)]·H2O (1) and [Zn­(TTDPb)­(bodca)]·H2O (2), were successfully designed and synthesized using 3,6-di­(pyridin-4-yl)­thieno­[3,2-b]­thiophene (TTDPa) and 2,5-di­(pyridin-4-yl)­thieno­[3,2-b]­thiophene (TTDPb) as ligands, in the presence of bicyclo[2.2.2]­octane-1,4-dicarboxylic acid (H2bodca). Both 1 and 2 display a three-dimensional (3D) structure with 5-fold interpenetration, and notably, 2 forms a larger one-dimensional pore measuring 17.16 × 10.81 Å2 in size. Fluorescence experiments demonstrate that 1 and 2 can function as luminescent sensors for nitrofurantoin (NFT) and nitrofurazone (NFZ) with low detection limits, remarkable selectivity, and good recyclability. A comprehensive analysis was conducted to investigate the differing sensing effects of compounds 1 and 2 and to explore potential sensing mechanisms. Additionally, at 328 K and 98% relative humidity, 1 and 2 exhibit proton conductivity values of 2.13 × 10–3 and 4.91 × 10–3 S cm–1, respectively, making them suitable proton-conducting materials. 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Chem</addtitle><description>Functionalized crystalline solids based on metal–organic frameworks (MOFs) enable efficient luminescence detection and high proton conductivity, making them crucial in the realms of environmental monitoring and clean energy. Here, two structurally and functionally distinct zinc-based MOFs, [Zn­(TTDPa)­(bodca)]·H2O (1) and [Zn­(TTDPb)­(bodca)]·H2O (2), were successfully designed and synthesized using 3,6-di­(pyridin-4-yl)­thieno­[3,2-b]­thiophene (TTDPa) and 2,5-di­(pyridin-4-yl)­thieno­[3,2-b]­thiophene (TTDPb) as ligands, in the presence of bicyclo[2.2.2]­octane-1,4-dicarboxylic acid (H2bodca). Both 1 and 2 display a three-dimensional (3D) structure with 5-fold interpenetration, and notably, 2 forms a larger one-dimensional pore measuring 17.16 × 10.81 Å2 in size. Fluorescence experiments demonstrate that 1 and 2 can function as luminescent sensors for nitrofurantoin (NFT) and nitrofurazone (NFZ) with low detection limits, remarkable selectivity, and good recyclability. A comprehensive analysis was conducted to investigate the differing sensing effects of compounds 1 and 2 and to explore potential sensing mechanisms. Additionally, at 328 K and 98% relative humidity, 1 and 2 exhibit proton conductivity values of 2.13 × 10–3 and 4.91 × 10–3 S cm–1, respectively, making them suitable proton-conducting materials. 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Chem</addtitle><date>2023-12-11</date><risdate>2023</risdate><volume>62</volume><issue>49</issue><spage>20314</spage><epage>20324</epage><pages>20314-20324</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Functionalized crystalline solids based on metal–organic frameworks (MOFs) enable efficient luminescence detection and high proton conductivity, making them crucial in the realms of environmental monitoring and clean energy. Here, two structurally and functionally distinct zinc-based MOFs, [Zn­(TTDPa)­(bodca)]·H2O (1) and [Zn­(TTDPb)­(bodca)]·H2O (2), were successfully designed and synthesized using 3,6-di­(pyridin-4-yl)­thieno­[3,2-b]­thiophene (TTDPa) and 2,5-di­(pyridin-4-yl)­thieno­[3,2-b]­thiophene (TTDPb) as ligands, in the presence of bicyclo[2.2.2]­octane-1,4-dicarboxylic acid (H2bodca). Both 1 and 2 display a three-dimensional (3D) structure with 5-fold interpenetration, and notably, 2 forms a larger one-dimensional pore measuring 17.16 × 10.81 Å2 in size. Fluorescence experiments demonstrate that 1 and 2 can function as luminescent sensors for nitrofurantoin (NFT) and nitrofurazone (NFZ) with low detection limits, remarkable selectivity, and good recyclability. A comprehensive analysis was conducted to investigate the differing sensing effects of compounds 1 and 2 and to explore potential sensing mechanisms. Additionally, at 328 K and 98% relative humidity, 1 and 2 exhibit proton conductivity values of 2.13 × 10–3 and 4.91 × 10–3 S cm–1, respectively, making them suitable proton-conducting materials. 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title Two Stable Bifunctional Zinc Metal–Organic Frameworks with Luminescence Detection of Antibiotics and Proton Conduction
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