A Study of the Behavior of Cadmium in Soil–Soil Solution–Plant System in a Model Experiment Using the 109Cd Radioactive Tracer
This article discusses the processes of transition to the aqueous phase and uptake from it by plants of stable (Cd) and radioactive ( 109 Cd) isotopes. Regularities of the distribution of Cd/ 109 Cd between different forms of their chemical compounds in the soil were revealed by means of sequential...
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| Veröffentlicht in: | Moscow University soil science bulletin 2022-12, Vol.77 (4), p.303-313 |
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| creator | Anisimov, V. S. Anisimova, L. N. Sanzharov, A. I. Korneev, Yu. N. Krylenkin, D. V. Shcheglov, A. I. Kolyagin, Yu. G. |
| description | This article discusses the processes of transition to the aqueous phase and uptake from it by plants of stable (Cd) and radioactive (
109
Cd) isotopes. Regularities of the distribution of Cd/
109
Cd between different forms of their chemical compounds in the soil were revealed by means of sequential extraction procedure (SEP) according to the Tessier–Förstner sceme. It was shown that the content of labile and conditionally labile forms of compounds (fraction F1-F3) of stable Cd was 1.2–1.8 times lower than that of radioactive
109
Cd and, conversely, fixed conservative forms of metal compounds (fraction F4–F6) by 2.4–5.3 times more. The Cd concentration,
109
Cd activity concentration, distribution and concentration coefficients of natural Cd and
109
Cd radionuclide, and accumulation and removal of metal by plants were evaluated. The values of enrichment factors of natural (stable) Cd contained in sequentially extracted chemical fractions by
109
Cd radioisotope were determined, and the value of pool of labile cadmium compounds in studied soil was calculated. Based on the results of solid-state
13
C NMR spectrometry, the qualitative composition of high-molecular organic compounds of the soil solution was determined and their ability to specifically sorb heavy-metal cations was assessed. |
| doi_str_mv | 10.3103/S0147687422040032 |
| format | Article |
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109
Cd) isotopes. Regularities of the distribution of Cd/
109
Cd between different forms of their chemical compounds in the soil were revealed by means of sequential extraction procedure (SEP) according to the Tessier–Förstner sceme. It was shown that the content of labile and conditionally labile forms of compounds (fraction F1-F3) of stable Cd was 1.2–1.8 times lower than that of radioactive
109
Cd and, conversely, fixed conservative forms of metal compounds (fraction F4–F6) by 2.4–5.3 times more. The Cd concentration,
109
Cd activity concentration, distribution and concentration coefficients of natural Cd and
109
Cd radionuclide, and accumulation and removal of metal by plants were evaluated. The values of enrichment factors of natural (stable) Cd contained in sequentially extracted chemical fractions by
109
Cd radioisotope were determined, and the value of pool of labile cadmium compounds in studied soil was calculated. Based on the results of solid-state
13
C NMR spectrometry, the qualitative composition of high-molecular organic compounds of the soil solution was determined and their ability to specifically sorb heavy-metal cations was assessed.</description><identifier>ISSN: 0147-6874</identifier><identifier>EISSN: 1934-7928</identifier><identifier>DOI: 10.3103/S0147687422040032</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>bulls ; Cadmium ; Cadmium compounds ; Cations ; Chemical compounds ; Earth and Environmental Science ; Earth Sciences ; Extraction procedures ; Heavy metals ; Historical Geology ; Isotopes ; Magnetic resonance spectroscopy ; Metal compounds ; Metal ions ; NMR ; Nuclear magnetic resonance ; Organic compounds ; Organic soils ; Paleontology ; Radioactive tracers ; Radioisotopes ; radiolabeling ; radionuclides ; soil ; Soil solution ; Soils ; Spectrometry ; spectroscopy</subject><ispartof>Moscow University soil science bulletin, 2022-12, Vol.77 (4), p.303-313</ispartof><rights>Allerton Press, Inc. 2022. ISSN 0147-6874, Moscow University Soil Science Bulletin, 2022, Vol. 77, No. 4, pp. 303–313. © Allerton Press, Inc., 2022. Russian Text © The Author(s), 2022, published in Vestnik Moskovskogo Universiteta, Seriya 17: Pochvovedenie, 2022, No. 4, pp. 106–116.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1462-70344facdc75c0f2f1ba7ba86306567a289759defcab4fc1de5e5d77e8a11bc23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.3103/S0147687422040032$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.3103/S0147687422040032$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Anisimov, V. S.</creatorcontrib><creatorcontrib>Anisimova, L. N.</creatorcontrib><creatorcontrib>Sanzharov, A. I.</creatorcontrib><creatorcontrib>Korneev, Yu. N.</creatorcontrib><creatorcontrib>Krylenkin, D. V.</creatorcontrib><creatorcontrib>Shcheglov, A. I.</creatorcontrib><creatorcontrib>Kolyagin, Yu. G.</creatorcontrib><title>A Study of the Behavior of Cadmium in Soil–Soil Solution–Plant System in a Model Experiment Using the 109Cd Radioactive Tracer</title><title>Moscow University soil science bulletin</title><addtitle>Moscow Univ. Soil Sci. Bull</addtitle><description>This article discusses the processes of transition to the aqueous phase and uptake from it by plants of stable (Cd) and radioactive (
109
Cd) isotopes. Regularities of the distribution of Cd/
109
Cd between different forms of their chemical compounds in the soil were revealed by means of sequential extraction procedure (SEP) according to the Tessier–Förstner sceme. It was shown that the content of labile and conditionally labile forms of compounds (fraction F1-F3) of stable Cd was 1.2–1.8 times lower than that of radioactive
109
Cd and, conversely, fixed conservative forms of metal compounds (fraction F4–F6) by 2.4–5.3 times more. The Cd concentration,
109
Cd activity concentration, distribution and concentration coefficients of natural Cd and
109
Cd radionuclide, and accumulation and removal of metal by plants were evaluated. The values of enrichment factors of natural (stable) Cd contained in sequentially extracted chemical fractions by
109
Cd radioisotope were determined, and the value of pool of labile cadmium compounds in studied soil was calculated. Based on the results of solid-state
13
C NMR spectrometry, the qualitative composition of high-molecular organic compounds of the soil solution was determined and their ability to specifically sorb heavy-metal cations was assessed.</description><subject>bulls</subject><subject>Cadmium</subject><subject>Cadmium compounds</subject><subject>Cations</subject><subject>Chemical compounds</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Extraction procedures</subject><subject>Heavy metals</subject><subject>Historical Geology</subject><subject>Isotopes</subject><subject>Magnetic resonance spectroscopy</subject><subject>Metal compounds</subject><subject>Metal ions</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic compounds</subject><subject>Organic soils</subject><subject>Paleontology</subject><subject>Radioactive tracers</subject><subject>Radioisotopes</subject><subject>radiolabeling</subject><subject>radionuclides</subject><subject>soil</subject><subject>Soil solution</subject><subject>Soils</subject><subject>Spectrometry</subject><subject>spectroscopy</subject><issn>0147-6874</issn><issn>1934-7928</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kc9KxDAQxoMouP55AG8BL16qkzRt2qMu_gNFcfVcsslUI91mTVpxb-Ir-IY-iakrCIqnmeH7fR8zDCE7DPZTBunBBJiQeSEF5yAAUr5CRqxMRSJLXqyS0SAng75ONkJ4BMhyLmBE3g7ppOvNgrqadg9Ij_BBPVvnh3mszMz2M2pbOnG2-Xh9H0rsm76zro3zdaPajk4WocMvTNFLZ7Chxy9z9HaGUbwLtr3_imZQjg29UcY6pTv7jPTWK41-i6zVqgm4_V03yd3J8e34LLm4Oj0fH14kmomcJxJSIWqljZaZhprXbKrkVBV5CnmWS8WLUmalwVqrqag1M5hhZqTEQjE21TzdJHvL3Ll3Tz2GrprZoLGJN6DrQ8WLQuZQABvQ3V_oo-t9G7eruMxZXEWCiBRbUtq7EDzW1TwerfyiYlANX6n-fCV6-NITItveo_9J_t_0CXYMj50</recordid><startdate>20221201</startdate><enddate>20221201</enddate><creator>Anisimov, V. 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S.</creatorcontrib><creatorcontrib>Anisimova, L. N.</creatorcontrib><creatorcontrib>Sanzharov, A. I.</creatorcontrib><creatorcontrib>Korneev, Yu. N.</creatorcontrib><creatorcontrib>Krylenkin, D. V.</creatorcontrib><creatorcontrib>Shcheglov, A. I.</creatorcontrib><creatorcontrib>Kolyagin, Yu. G.</creatorcontrib><collection>CrossRef</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Moscow University soil science bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Anisimov, V. S.</au><au>Anisimova, L. N.</au><au>Sanzharov, A. I.</au><au>Korneev, Yu. N.</au><au>Krylenkin, D. V.</au><au>Shcheglov, A. I.</au><au>Kolyagin, Yu. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Study of the Behavior of Cadmium in Soil–Soil Solution–Plant System in a Model Experiment Using the 109Cd Radioactive Tracer</atitle><jtitle>Moscow University soil science bulletin</jtitle><stitle>Moscow Univ. Soil Sci. Bull</stitle><date>2022-12-01</date><risdate>2022</risdate><volume>77</volume><issue>4</issue><spage>303</spage><epage>313</epage><pages>303-313</pages><issn>0147-6874</issn><eissn>1934-7928</eissn><abstract>This article discusses the processes of transition to the aqueous phase and uptake from it by plants of stable (Cd) and radioactive (
109
Cd) isotopes. Regularities of the distribution of Cd/
109
Cd between different forms of their chemical compounds in the soil were revealed by means of sequential extraction procedure (SEP) according to the Tessier–Förstner sceme. It was shown that the content of labile and conditionally labile forms of compounds (fraction F1-F3) of stable Cd was 1.2–1.8 times lower than that of radioactive
109
Cd and, conversely, fixed conservative forms of metal compounds (fraction F4–F6) by 2.4–5.3 times more. The Cd concentration,
109
Cd activity concentration, distribution and concentration coefficients of natural Cd and
109
Cd radionuclide, and accumulation and removal of metal by plants were evaluated. The values of enrichment factors of natural (stable) Cd contained in sequentially extracted chemical fractions by
109
Cd radioisotope were determined, and the value of pool of labile cadmium compounds in studied soil was calculated. Based on the results of solid-state
13
C NMR spectrometry, the qualitative composition of high-molecular organic compounds of the soil solution was determined and their ability to specifically sorb heavy-metal cations was assessed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.3103/S0147687422040032</doi><tpages>11</tpages></addata></record> |
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| subjects | bulls Cadmium Cadmium compounds Cations Chemical compounds Earth and Environmental Science Earth Sciences Extraction procedures Heavy metals Historical Geology Isotopes Magnetic resonance spectroscopy Metal compounds Metal ions NMR Nuclear magnetic resonance Organic compounds Organic soils Paleontology Radioactive tracers Radioisotopes radiolabeling radionuclides soil Soil solution Soils Spectrometry spectroscopy |
| title | A Study of the Behavior of Cadmium in Soil–Soil Solution–Plant System in a Model Experiment Using the 109Cd Radioactive Tracer |
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